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| Open AccessAligned macrocycle pores in ultrathin films for accurate molecular sieving
Selectively functionalized macrocycles were synthesized with reactivities that preferentially aligned to create well-defined pores across an ultrathin nanofilm offering a strategy to create subnanometre channels in polymer membranes, and demonstrating potential for accurate molecular separations.
- Zhiwei Jiang
- , Ruijiao Dong
- & Andrew G. Livingston
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Fast-charging aluminium–chalcogen batteries resistant to dendritic shorting
An aluminium–chalcogen battery operating with a molten-salt electrolyte composed of NaCl–KCl–AlCl3 is presented, which allows rapid charging at up to 200C for hundreds of cycles, and is scalable, fire-resistant and low cost.
- Quanquan Pang
- , Jiashen Meng
- & Donald R. Sadoway
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Article |
Floating perovskite-BiVO4 devices for scalable solar fuel production
This work introduces lightweight, leaf-like photoelectrochemical devices for unassisted water splitting and syngas production, which could be used in the fabrication of floating systems for solar fuel production.
- Virgil Andrei
- , Geani M. Ucoski
- & Erwin Reisner
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Perovskite superlattices with efficient carrier dynamics
Fabrication of a low-dimensional metal halide perovskite superlattice by chemical epitaxy is reported, with a criss-cross two-dimensional network parallel to the substrate, leading to efficient carrier transport in three dimensions.
- Yusheng Lei
- , Yuheng Li
- & Sheng Xu
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Dislocation-induced stop-and-go kinetics of interfacial transformations
Environmental transmission electron microscopy is used to reveal that mismatch dislocations modulate the interfacial transformation of copper oxide to copper metal in an intermittent manner.
- Xianhu Sun
- , Dongxiang Wu
- & Guangwen Zhou
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Atomic imaging of zeolite-confined single molecules by electron microscopy
Using integrated differential phase contrast scanning transmission electron microscopy, the atomic imaging of single pyridine and thiophene molecules identifies host–guest interactions in zeolite ZSM-5 and their adsorption and desorption behaviours can be studied.
- Boyuan Shen
- , Huiqiu Wang
- & Fei Wei
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Asymmetric pore windows in MOF membranes for natural gas valorization
A metal–organic framework membrane based on fumarate and mesaconate linkers is shown to have a pore aperture shape that enables efficient and cost-effective removal of nitrogen and carbon dioxide from methane.
- Sheng Zhou
- , Osama Shekhah
- & Mohamed Eddaoudi
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Origin of structural degradation in Li-rich layered oxide cathode
Diffractive imaging of an important class of battery electrodes during cycling shows that lattice strain is a crucial yet overlooked factor that contributes to voltage fade over time.
- Tongchao Liu
- , Jiajie Liu
- & Khalil Amine
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Local nanoscale phase impurities are degradation sites in halide perovskites
A multimodal microscopy toolkit reveals nanoscale defect clusters in halide perovskite films and that these clusters are sites at which photochemical degradation seeds.
- Stuart Macpherson
- , Tiarnan A. S. Doherty
- & Samuel D. Stranks
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Revitalizing interface in protonic ceramic cells by acid etch
A simple acid treatment can improve high-temperature annealed electrolyte surfaces, resulting in improved performance and stability at lower temperatures for protonic ceramic fuel/electrolysis cells, offering new understanding for sustainable energy infrastructures.
- Wenjuan Bian
- , Wei Wu
- & Dong Ding
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Perovskite–organic tandem solar cells with indium oxide interconnect
A thin low-loss indium oxide interconnect layer grown by atomic layer deposition enables perovskite–organic hybrid tandem solar cells with a high open-circuit voltage and a high power conversion efficiency.
- K. O. Brinkmann
- , T. Becker
- & T. Riedl
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Article
| Open AccessReconstructed covalent organic frameworks
A protocol in which monomers are pre-organized using a reversible and removable urea linkage enables the production of covalent organic frameworks with higher crystallinity and porosity than those produced using standard approaches with randomly aligned monomers.
- Weiwei Zhang
- , Linjiang Chen
- & Andrew I. Cooper
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Stability-limiting heterointerfaces of perovskite photovoltaics
Surface treatments for the passivation of defects in perovskite solar cells have a detrimental side effect that limits the maximum stability improvement.
- Shaun Tan
- , Tianyi Huang
- & Yang Yang
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Perspective |
Towards enduring autonomous robots via embodied energy
The concept of 'Embodied Energy'—in which the components of a robot or device both store energy and provide a mechanical or structural function—is put forward, along with specific robot-design principles.
- Cameron A. Aubin
- , Benjamin Gorissen
- & Robert F. Shepherd
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Centimetre-scale perovskite solar cells with fill factors of more than 86 per cent
Perovskite solar cells including charge transport material fabricated using a reverse-doping process have the highest certified efficiency for cells of 1-cm2 active area and the highest fill factor reported so far.
- Jun Peng
- , Felipe Kremer
- & Kylie R. Catchpole
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All-perovskite tandem solar cells with improved grain surface passivation
A certified efficiency of 26.4% in all-perovskite tandem solar cells, exceeding that of the best-performing single-junction perovskite solar cells, is achieved by control over surface defects in the Pb–Sn subcell.
- Renxing Lin
- , Jian Xu
- & Hairen Tan
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Elastomeric electrolytes for high-energy solid-state lithium batteries
An elastomeric solid-state electrolyte shows desirable mechanical properties and high electrochemical stability, and is used to demonstrate a high-energy solid-state lithium battery at ambient temperature.
- Michael J. Lee
- , Junghun Han
- & Seung Woo Lee
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Article
| Open AccessIn situ formation of ZnOx species for efficient propane dehydrogenation
Propene is obtained through propane dehydrogenation using catalysts that are toxic, expensive or demanding to regenerate with ecologically harmful compounds, but the ZnO-based alternative reported here is cheap, clean and scalable.
- Dan Zhao
- , Xinxin Tian
- & Evgenii V. Kondratenko
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Transition metal-catalysed molecular n-doping of organic semiconductors
Electron doping of organic semiconductors is typically inefficient, but here a precursor molecular dopant is used to deliver higher n-doping efficiency in a much shorter doping time.
- Han Guo
- , Chi-Yuan Yang
- & Xugang Guo
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Copper-coordinated cellulose ion conductors for solid-state batteries
By coordinating copper ions with the oxygen-containing groups of cellulose nanofibrils, the molecular spacing in the nanofibrils is increased, allowing fast transport of lithium ions and offering hopes for solid-state batteries.
- Chunpeng Yang
- , Qisheng Wu
- & Liangbing Hu
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Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes
An atomically coherent interlayer between the electron-transporting and perovskite layers in perovskite solar cells enhances charge extraction and transport from the perovskite, enabling high power conversion efficiency.
- Hanul Min
- , Do Yoon Lee
- & Sang Il Seok
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Mastering the surface strain of platinum catalysts for efficient electrocatalysis
By depositing platinum shells on palladium-based nanocubes, the strain can be controlled by through phosphorization and dephosphorization, making it possible to tune the electrocatalytic activity of the platinum shells.
- Tianou He
- , Weicong Wang
- & Mingshang Jin
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The role of charge recombination to triplet excitons in organic solar cells
A substantial pathway for energy loss in organic solar cells may be suppressed by engineering hybridization between non-fullerene acceptor triplet excitons and spin-triplet charge transfer excitons.
- Alexander J. Gillett
- , Alberto Privitera
- & Richard H. Friend
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Photocatalytic solar hydrogen production from water on a 100-m2 scale
Carbon-neutral hydrogen can be produced through photocatalytic water splitting, as demonstrated here with a 100-m2 array of panel reactors that reaches a maximum conversion efficiency of 0.76%.
- Hiroshi Nishiyama
- , Taro Yamada
- & Kazunari Domen
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Rechargeable Na/Cl2 and Li/Cl2 batteries
Rechargeable Na/Cl2 and Li/Cl2 batteries are produced with a microporous carbon positive electrode, aluminium chloride in thionyl chloride as the electrolyte, and either sodium or lithium as the negative electrode.
- Guanzhou Zhu
- , Xin Tian
- & Hongjie Dai
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Perspective |
Designing the next generation of proton-exchange membrane fuel cells
This Perspective reviews the recent technical developments in the components of the fuel cell stack in proton-exchange membrane fuel cell vehicles and outlines the road towards large-scale commercialization of such vehicles.
- Kui Jiao
- , Jin Xuan
- & Michael D. Guiver
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Operando optical tracking of single-particle ion dynamics in batteries
The dynamics of ions within a working lithium-ion battery are examined using optical interferometric scattering microscopy, which allows ion transport to be related to phase transitions and microstructural features.
- Alice J. Merryweather
- , Christoph Schnedermann
- & Akshay Rao
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Tomographic reconstruction of oxygen orbitals in lithium-rich battery materials
High-energy X-ray Compton measurements and first-principles modelling reveal how the electronic orbital responsible for the reversible anionic redox activity can be imaged and visualized, and its character and symmetry determined.
- Hasnain Hafiz
- , Kosuke Suzuki
- & Venkatasubramanian Viswanathan
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CO2 doping of organic interlayers for perovskite solar cells
CO2 and ultraviolet light are used to initiate the p-type doping of spiro-OMeTAD:LiTFSI films, which show enhanced efficiencies when used as hole-transporting layers in solar cells and have shorter fabrication times compared with interlayers doped using conventional methods.
- Jaemin Kong
- , Yongwoo Shin
- & André D. Taylor
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Article |
A dynamic stability design strategy for lithium metal solid state batteries
A multi-layered electrolyte, in which a less stable electrolyte is sandwiched between two electrolyte layers that are more stable, can inhibit the growth of lithium dendrites in highly pressurized solid-state lithium metal batteries.
- Luhan Ye
- & Xin Li
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Correlative operando microscopy of oxygen evolution electrocatalysts
Mapping the operational chemical, physical and electronic structure of an oxygen evolution electrocatalyst at the nanoscale links the properties of the material with the observed oxygen evolution activity.
- J. Tyler Mefford
- , Andrew R. Akbashev
- & William C. Chueh
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Polypeptide organic radical batteries
An environmentally friendly, all-organic radical battery is demonstrated, in which redox-active polypeptides perform as both cathode and anode materials, with a metal-free organic electrolyte.
- Tan P. Nguyen
- , Alexandra D. Easley
- & Karen L. Wooley
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Article |
A single-molecule van der Waals compass
The orientation of a rotating para-xylene molecule in the nanochannel of a zeolite framework can be visualised by electron microscopy to determine the host–guest van der Waals interaction inside the channel.
- Boyuan Shen
- , Xiao Chen
- & Fei Wei
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Article |
A highly stable and flexible zeolite electrolyte solid-state Li–air battery
Flexible, stable and energy-dense solid-state Li–air batteries are realised using ultrathin, chemically inert ion-conductive zeolite membranes as a solid electrolyte.
- Xiwen Chi
- , Malin Li
- & Jihong Yu
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Article |
Diversity-oriented synthesis of polymer membranes with ion solvation cages
A diversity-oriented synthesis approach that yields a library of architecturally broad microporous polymers is used to develop structurally diverse polymer membranes with ion specificity and to screen their properties.
- Miranda J. Baran
- , Mark E. Carrington
- & Brett A. Helms
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Article |
Pseudo-halide anion engineering for α-FAPbI3 perovskite solar cells
Incorporation of the pseudo-halide anion formate during the fabrication of α-FAPbI3 perovskite films eliminates deleterious iodide vacancies, yielding solar cell devices with a certified power conversion efficiency of 25.21 per cent and long-term operational stability.
- Jaeki Jeong
- , Minjin Kim
- & Jin Young Kim
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Article |
Thermal-expansion offset for high-performance fuel cell cathodes
Highly active but durable perovskite-based solid oxide fuel cell cathodes are realized using a thermal-expansion offset, achieving full thermo-mechanical compatibility between the cathode and other cell components.
- Yuan Zhang
- , Bin Chen
- & Zongping Shao
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Article |
Efficient perovskite solar cells via improved carrier management
An improved device design for perovskite-based photovoltaic cells enables a certified power conversion efficiency of 25.2 per cent, translating to 80.5 per cent of the thermodynamic limit for its bandgap, which approaches those achieved by silicon solar cells.
- Jason J. Yoo
- , Gabkyung Seo
- & Jangwon Seo
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Article |
A stable low-temperature H2-production catalyst by crowding Pt on α-MoC
A stable, low-temperature water–gas shift catalyst is achieved by crowding platinum atoms and clusters on α-molybdenum carbide; the crowding protects the support from oxidation that would cause catalyst deactivation.
- Xiao Zhang
- , Mengtao Zhang
- & Ding Ma
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Key role of chemistry versus bias in electrocatalytic oxygen evolution
Spectroscopic studies and theoretical calculations of the electrocatalytic oxygen evolution reaction establish that reaction rates depend on the amount of charge stored in the electrocatalyst, and not on the applied potential.
- Hong Nhan Nong
- , Lorenz J. Falling
- & Travis E. Jones
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Article |
Near-perfect photon utilization in an air-bridge thermophotovoltaic cell
An air gap embedded within the structure of a thermophotovoltaic device acts as a near-perfect reflector of low-energy photons, resulting in their recovery and recycling by the thermal source, enabling excellent power-conversion efficiency.
- Dejiu Fan
- , Tobias Burger
- & Stephen R. Forrest
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Article |
Filling metal–organic framework mesopores with TiO2 for CO2 photoreduction
Investigation of a chromium-based metal–organic framework shows that the location of added TiO2 inside specific mesopores strongly affects the ability of the material to catalyse photoreduction of CO2.
- Zhuo Jiang
- , Xiaohui Xu
- & Hexiang Deng
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A disordered rock salt anode for fast-charging lithium-ion batteries
A vanadium-based lithium-rich disordered rock salt oxide is shown to work as a low-potential anode with rapid intercalation kinetics for lithium-ion batteries.
- Haodong Liu
- , Zhuoying Zhu
- & Ping Liu
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Article |
Additive manufacturing of silica aerogels
A direct ink writing protocol for silica aerogels enables 3D printing of lightweight, miniaturized objects with complex shapes, with the possibility to easily add functionality by incorporating nanoparticles.
- Shanyu Zhao
- , Gilberto Siqueira
- & Wim J. Malfait
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Vacancy-enabled N2 activation for ammonia synthesis on an Ni-loaded catalyst
Ammonia is synthesized using a dual-site approach, whereby nitrogen vacancies on LaN activate N2, which then reacts with hydrogen atoms produced over the Ni metal to give ammonia.
- Tian-Nan Ye
- , Sang-Won Park
- & Hideo Hosono
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Photocatalytic water splitting with a quantum efficiency of almost unity
Water splitting with an internal quantum efficiency of almost unity is achieved using a modified semiconductor photocatalyst that selectively promotes the hydrogen and oxygen evolution reactions on separate crystal facets.
- Tsuyoshi Takata
- , Junzhe Jiang
- & Kazunari Domen
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Accelerated discovery of CO2 electrocatalysts using active machine learning
Machine learning predicts Cu-Al electrocatalysts provide better efficiency and productivity than copper when using intermittent renewable electricity to convert carbon dioxide to useful chemicals and fuels.
- Miao Zhong
- , Kevin Tran
- & Edward H. Sargent
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Article |
Iron-based binary ferromagnets for transverse thermoelectric conversion
Aluminium- and gallium-doped iron compounds show a large anomalous Nernst effect owing to a topological electronic structure, and their films are potentially suitable for designing low-cost, flexible microelectronic thermoelectric generators.
- Akito Sakai
- , Susumu Minami
- & Satoru Nakatsuji
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Article |
On-device lead sequestration for perovskite solar cells
Using lead-absorbing materials to coat the front and back of perovskite solar cells can prevent lead leaching from damaged devices, without affecting the device performance or long-term operation stability.
- Xun Li
- , Fei Zhang
- & Tao Xu