Abstract
Albite is one of the major constituents in the crust. We report here that albite, when subjected to hydrous cold subduction conditions, undergoes hitherto unknown breakdown into hydrated smectite, moganite, and corundum, above 2.9 GPa and 290 °C or about 90 km depth conditions, followed by subsequent breakdown of smectite into jadeite above 4.3 GPa and 435 °C or near 135 km depth. Upon the hydration into smectite, the fluid volume of the system decreases by ~14 %, whereas it increases by ~8 % upon its dehydration into jadeite. Both the hydration and dehydration depths are correlated to increases in seismicity by 93 % and 104 %, respectively, along the South Mariana trench over the past 5 years. Moreover, the formation of smectite is accompanied by the release of OH− species, which would explain the formation of moganite and expected alkalinity of the subducting fluid. Thus, we shed new insights into the mechanism of water transport and related geochemical and geophysical activities in the contemporary global subduction system.
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Introduction
Subduction zones are important geochemical and geophysical interfaces as oceanic plates sink deep into the Earth transporting and cycling rocks and volatile components, such as water and carbon dioxide, between the surface and the mantle1,2,3,4. Understanding the mineral–water interaction along subduction zone conditions is therefore critical as it is related to metamorphism, magma generation, and earthquake triggering along the subducting plate3,5,6,7,8,9,10,11 and in the overlying mantle wedge2. Alkali feldspars are important components of the subducting oceanic plate that have been used to model the generation of magma and the evolution of lithospheric mantle composition12,13,14.
Amongst alkali feldspars, albite [NaAlSi3O8] accounts ~16% and ~10% in volume in basalt and gabbro in the oceanic crust, respectively8. Generally, anhydrous albite has been reported to transform to jadeite and quartz under high temperature–pressure conditions in the range of 1–3 GPa and 200–1000 °C7,15,16. On the other hand, Shen and Keppler reported complete miscibility between silicate melts and hydrous fluids in the near surface conditions from visual observations in the albite–H2O system13.
A series of mineral transformations have been established along diverse subduction geotherms in relation to the observed metamorphic facies17,18. Dehydration and breakdown of hydrous minerals down to ca. 240 km depth are believed to impact the chemical and physical properties of subducting rocks9,19. It is uncertain, however, how mineral transformation is related to the chemistry of subduction fluids, specially its mildly alkaline nature. Galvez et al. reported that the degree of ∆pH may be caused by intramantle differentiation or infiltration of fluids enriched in alkali components extracted from the subducted crust3. In this study, we report the first experimental evidence of alkaline fluid generation from the breakdown reaction in the anhydrous albite–water system under cold subducting slab conditions down to about 170 km in depth. We found that starting at 2.9 GPa and 290 °C or about 90 km depth along cold subducting slab, albite breaks down to form a mixture of smectite, moganite, and corundum, which releases OH− species in a 5:4 molar ratio. We suspect that this would impact the pH of subducting fluid by as much as ∆pH of 2.2–2.5, which is extrapolated from the calculation of ∆pH of solutions in equilibrium with subducting basaltic slab3.
In this work, we performed in situ high-pressure and -temperature synchrotron X-ray diffraction (XRD) experiments under three different sample conditions using a resistive-heating diamond anvil cell (DAC): (1) up to 5.4 GPa and 570 °C (cold subduction slab and wet condition, down to ca. 170 km depth); (2) up to 3.2 GPa and 530 °C (warm subduction slab and wet condition, down to ca. 100 km depth); (3) up to 4.7 GPa and 505 °C (cold subduction slab and dry condition, down to ca. 145 km depth). In wet condition experiments, powdered samples of albite were immersed in water in a ca. 1:1 by volume ratio as a pressure-transmitting medium (PTM). In dry condition experiment, no PTM was added to anhydrous albite.
Results
In situ high-pressure and high-temperature studies using a DAC
Upon increase in pressure and temperature in wet and cold subduction conditions following the geothermal gradients along the South Mariana trench20, we observed that albite breaks down to hydrated Na-smectite (beidellite), moganite, and corundum above 2.9 GPa and 290 °C or about 90 km depth, as below (Fig. 1 and Supplementary Fig. 1).
The appearance of the characteristic (001) diffraction peak at d001 ~12 Å indicates that the newly formed Na-smectite is hydrated with one layer of water with a total water content of ca. 9.0 wt.% (Fig. 2a). In a smectite clay structure, it has been established that the interlayer is mono-hydrated (1W model) when d001 is in the range between 11.8–12.9 Å21,22. The observed transformation of albite along the hydrous cold subduction conditions thus reveal hitherto unknown breakdown reaction to form a hydrated clay mineral, which is quite different from the established breakdown scheme of albite to jadeite and quartz in anhydrous medium above P = 0.035 + 0.00265 T (°C) ± 0.05 GPa7,15,16.
The other crystalline by-product along with the hydrated smectite, moganite, is known to be a stable polymorph of quartz under alkaline environment in the pH range between 9.5 and 10.5 (or ∆pH of 2.5–3.5 range)23. In fact, the breakdown reaction (1) requires the release of Na(OH), which is expected to be dissolved in the remaining fluid medium under our experimental conditions and hence not detectable in the observed XRD pattern. Further increase in pressure and temperature above 4.3 GPa and 435 °C, i.e., near 135 km depth conditions, results in the breakdown of the hydrated Na-smectite as the characteristic d001 ~12 Å peak disappears24, as below (Fig. 2).
Interestingly, when the thermal gradient follows that of warm subduction slab in the presence of water as a PTM, we observed the partial breakdown of albite into jadeite (NaAlSi2O6) and α-quartz (SiO2) above 2.2 GPa and 375 °C or ca. 70 km depth conditions but could not observe the formation of the hydrated Na-smectite from albite up to 3.2 GPa and 530 °C or ca. 100 km depth conditions (Figs. 1, 2b, and Supplementary Fig. 3b). When the experiments are repeated under dry conditions along the cold subduction zone, we also observed the previously known breakdown of albite into jadeite and α-quartz above 4.3 GPa and 385 °C or ca. 135 km depth conditions (Figs. 1, 2c, and Supplementary Fig. 3c)15,25. As for the formation of the quartz, it has been known that the compression of the α-quartz would bypass the stability field of coesite under certain non-hydrostatic compression26. Overall, our experimental results manifest that the hydration breakdown of albite into smectite and release of Na(OH) is specific for the hydrous cold subduction environments (Figs. 1, 2a, and Supplementary Fig. 3a) and hence the contemporary global subduction system20.
Scanning electron microscopy and FT-IR measurements on the starting and recovered samples
In order to confirm the hydration breakdown reaction of albite into the hydrated smectite and concurrent release of Na+ and (OH)− into the surrounding fluid medium, scanning electron microscopy (SEM) and FT-IR measurements were performed on the starting and recovered samples. The SEM images show unambiguous transformation in the crystal morphology from albite into the smectite clay in the recoverd sample under wet conditions (Fig. 3). Mid-IR spectra from the recovered sample also reveal new features in absorbance spectrum at 3484 cm−1 and 3587.8 cm−1 (inset in Fig. 3b). The latter vibration is identified as the IR-active stretch mode of OH in Na(OH)27, while the former broad streching band indicates the presence of interlayer water molecules in the 1W Na-smectite28. We thus confirm the reaction (1) where anhydrous albite under hydrous cold subduction conditions breaks down into a hydrated clay mineral, a quartz polymorph, and corundum by releasing Na+ and (OH)− species to form alkaline fluid environment. Up to our knowledge, this is the first experimental observation of breakdown into a hydrated clay and release of alkaline species from subducting oceanic crustal mineral29. Considering the estimated content of albite in basalt, i.e., ~16% in volume, in the subducting oceanic crust, our experimental design of the 1:1 volume mixture of albite and water translates to the water contents of ca. 5 wt.% H2O, which is assumed to be the water content in the cold subduction zone9,30,31. Furthermore, the formation of the hydrated Na-smectite from albite is confirmed by XRD and SEM measurements on the quenched samples from ex situ large volume press syntheses at 2.4 GPa and 260 °C conditions using lower water-to-sample ratios from 50 wt.% H2O down to 6 wt.% H2O (Fig. 3c and Supplementary Data Fig. 2). Our lowest water-to-albite ratio of 6 wt.% H2O would then translate to the basalt with ca. 0.9 wt.% H2O. According to van Keken et al.9, the water content of basalt at 90 km depth in a cold subducting slab, which is the depth of our hydration breakdown of albite, would be maintained to be over 2 wt.%, while warm subducting slabs would be almost dehydrated by ca. 90 km. Therefore, our experimental conditions would simulate that if hydrous minerals contribute water down to ca. 90 km depth to make the cold subducting slab wet, the hydration breakdown of albite into smectite would occur.
Ex situ high-pressure and high-temperature studies with a modified Griggs apparatus
In order to complement our experimental findings using a single mineral phase in a DAC, we have expanded our investigation into a macroscopic scale using a natural basalt rock containing ca. 66 vol.% of feldspars. Two sets of 3 mm diameter core-drilled samples of a basalt were heated at 250 °C and 2.5 GPa for 10 h using a modified Griggs apparatus (Fig. 1). In order to simulate hydrous conditions expected along the cold subduction system, one set was contained with ca. 5.5 wt.% of water in a sealed platinum capsule, while the other was treated without water. The recovered sample from the wet run showed that sample has been severely eroded, compared to the fresh sample from the dry run (Fig. 3). XRD data clearly revealed the presence of ~12.9 Å peak in the sample recovered from the wet run (Supplementary Fig. 4).
Discussion
The observed sequential breakdowns from albite lead to significant changes in the net crystalline density (see “Methods” and Supplementary Table 1). When albite breaks down into the smectite mixture at ca. 90 km depth conditions, the net crystalline density increases, i.e., from 2.58(1) g cm−3 to 2.63(1) g cm−3, as the 1W Na-smectite, moganite, and corundum form with densities of 1.76(1) g cm−3, 2.62(1) g cm−3, and 3.90(1) g cm−3, respectively, in the molar ratio shown in the reaction scheme (1). Subsequently upon the breakdown of the 1W Na-smectite at ca. 135 km depth conditions, the net crystalline density then increases by ca. 11% from 2.68(1) g cm−3 to 2.98(1) g cm−3. On the other hand, if we assume the starting volume of water is the same as that of albite, the net fluid volume would decrease by ca. 14%, e.g., from 1 m3 to 0.86 m3, upon the formation of the 1W Na-smectite at ca. 90 km depth, and then increase by ca. 8%, e.g., from 0.86 m3 to 0.93 m3, upon the breakdown of the 1W Na-smectite at ca. 135 km depth (Supplementary Table 1). The increase in the net fluid volume would correspond to ca. 9 wt.% release of water, which is higher than the amount of water released by the dehydration breakdown of hydrated subducting minerals such as phengite and amphibole, i.e., ca. 4.3 wt.% and 2 wt.%, respectively32. When we extend the estimated changes of the net density and fluid volume to subducting basalt composed of ~16 vol.% of albite, the degree of changes in the net density is modulated compared to those based on albite alone, i.e., the net density of the basalt is 3.16(1) g cm−3 at ambient condition, increases to 3.17(1) g cm−3 upon the formation of the hydrated smectite at ca. 90 km depth, and then further increases to 3.22 g cm−3 upon the breakdown of the hydrated smectite into jadeite and quartz at ca. 135 km depth. However, the degree of changes in the net fluid volume is comparable to the changes estimated based on albite alone, i.e., concomitant to the discontinuous changes in the net density of basalt, the net fluid volume decreases by ca. 11.5% and then increases by ca. 6%. Such concerted and discontinuous changes in the net fluid volume and crystalline density via hydration (reaction 1) and subsequent dehydration (reaction 2) breakdowns would impact the physical properties of the subducting slab itself and hence the earthquake-triggering mechanism in the depth range between ca. 90 and 135 km along the cold subducting slabs.
Seismic data along the South Mariana trench are in line with our observations that the intermediate-depth earthquakes increase by ca. 93% as the depth range increases from 70–90 km to 90–110 km (International Seismological Centre, ISC Bulletin), which is close to the region of the observed hydration breakdown of albite into a smectite clay. Ikari and Kopf, and Hirono et al. have recently shown that the presence of low-friction clay minerals such as smectite may play an important role in the dynamic weakening processes33,34. Based on the friction experiments simulating plate convergence rates of centimeters per year, they discovered unstable slip behavior in clay-dominated faults. The low shear strength of weak clay minerals in clayey fault would favor earthquake rupture accompanying large slip. Our results thus extend such a clay-mediated earthquake generation to deeper depths along subduction zone. At the depth range of 110–130 km, the frequency of earthquake occurrence decreases in comparison to the 90–110 km region. In the 130–150 km region, the earthquake frequency increases again by ca. 104%, which is the region where the dehydration breakdown of the smectite clay into jadeite occurs (Fig. 4). This can be well associated with the established dehydration embrittlement theory for intermediate-depth earthquakes35. In order to distinguish our new finding of the formation of hydrated clay mineral along cold subduction zone and its association with seismicity increase from dehydration embrittlement, we propose a new term, “hydration faulting (or smectization faulting)” as a possible new mechanism of subduction zone earthquakes. We encourage future studies to test our hypothesized mechanism that the increased seismicity is mainly from this hydration-related dynamic weakening process, and such phenomenon can be found in other subduction zones.
Furthermore, our results help us gain new insights into the geochemical processes occurring along cold subduction zones where fluid is transported deep into the mantle (Fig. 4)9,36. The extrapolated ∆pH of fluid in equilibrium with subducting basaltic slab3 to the temperature where the hydration breakdown of albite into a smectite clay has been observed is ca. 2.5, which is within the ∆pH range for the concurrent formation of moganite. The origin of calc-alkaline magma in the overriding mantle wedge might also be related to the breakdown of albite and release of Na(OH) to the surrounding fluid37.
Our results also shed new insights into interpreting anomalies in electrical and seismic properties along cold subduction zones. It has been suspected that the presence of hydrous minerals and/or increased melt/fluid fractions enhance electrical conductivity and seismic wave attenuation along with the thermal gradient of the subduction zone38. The conductivity model by Ni et al. and Pommier et al. proposes that the addition of ca. 7 wt.% H2O to basalt at 1200 °C explains the difference in electrical conductivity between North Chile (ca. 0.04–0.1 S m−1) and Mariana (ca. 0.01 S m−1)38,39. It has been known that warm slab, such as North Chile slab, may have released most of its aqueous fluids by ca. 90 km depth, whereas cold slab, such as Mariana slab, can still hold the fluids beyond 90 km depth, enriching partial melt accumulation zones with aqueous phases and leading to lower conductivity values39. Our observation on albite subjected to such hydrous cold subduction conditions supports these by showing the hydration breakdown of albite into smectite clay near ca. 90 km depths removing ca. 14 vol.% of fluid from the region (assuming a 1:1 mixture of albite and water) and then subsequent dehydration breakdown of smectite into jadeite above ca. 135 km depth releasing ca. 8 vol.% of fluid into the region.
Methods
Sample
The albite sample used in our DAC experiments is from Cheshire county in New Hampshire, USA. Initial elemental characterization was performed using X-ray fluorescence (XRF, M4 Tornado, Bruker Co.) and XRD (MicroMax-007HF, Rigaku Corp.). For XRF, a combination of 25 µm diameter X-ray from polycapillary lens and XFlash silicon drift detector was used to measure relative elemental concentrations at several points on a bulky albite crystal in vacuum. The composition of the albite sample was derived to be Na1.05K0.002Ca0.001Al1Si2.98O8. XRD was performed using a combination of 200 µm diameter X-ray (Mo-Kα1, λ = 0.709317(1) Å) and an imaging plate (IP) detector (R-axis IV++, Rigaku Corp.) in transmission geometry. The sample-to-detector distance was 150 mm and the exposure time was 10 min. Sample was contained in a boron capillary with an inner diameter of 0.3 mm and rotated between 0 to 180° during measurement for better powder averaging. LaB6 (NIST SRM 660c, a = 4.15704(8) Å) standard powder was used to derive the instrumental parameters. IPanalyzer v3.8 program was used to calibrate and process the 2D diffraction images.
Scanning electron microscopy
Field emission scanning electron microscopy (FE-SEM, JEOL-7800F) was performed on the original albite (ca. ×40,000) and its recovered products (ca. × 20,000). Each sample was coated in platinum (Sputter coater 108auto, Cressington Scientific Instruments) and measured for 120 s in vacuum. The images were measured under LED (lower electron detector) mode at 10 kV.
High-pressure and high-temperature synchrotron XRD
In situ high-pressure and -temperature XRD experiments were performed at the 3D beamline at Pohang Accelerator Laboratory (PAL). Monochromatic X-ray with 0.6888(1) Å (18 keV) in wavelength and 100 μm in size was provided using a DCM (double crystal monochromator) of bent Si (111) and Si (311) crystals. Angle-dispersive XRD data were measured using an image plate detector (MarXperts Mar345, 3000 × 3000 pixels, exposure time of 400 s). CeO2 (NIST SRM 674b, a = 5.4115(3) Å) standard powder was used for the instrument calibration. As a pressure vessel, a symmetric-type diamond-anvil cell (SDAC) was used in combination with a membrane-driven pressure control system (GE Pace5000). The culet diameter of the diamond anvil (type I) was 500 μm. A rhenium gasket was used after indentation to about 100 μm in thickness. A sample chamber of 150 μm in diameter was made in the gasket using an electric discharge machine (EDM; Holozoic products). Pure water was used as a PTM in the case of aqueous conditions experiments. Simultaneous P-T condition was created by using a set of house-made resistive coil heater (Kanthal-A1 wire of 26 gauge and ϕ 0.4 mm with a DC power supply by Sorensen XG 60-14, Ametek Inc.) to surround each diamond anvil40. Temperature was monitored using a K-type thermocouple attached to the pavilion of the diamond anvil close to the sample with the maximum uncertainties of ±3 °C41, and the sample pressure was estimated using the equation of state of the Au pressure marker. XRD at each PT step was measured for 400 s while rocking the DAC by 4°.
Infrared spectroscopy
Synchrotron IR experiments were performed at the beamline 12D at PAL. FT-IR spectra were measured in the mid-IR range (700–7000 cm−1) using a Vertex 80v + Hyperion 3000 microscope with ×15 objective and a mercury cadmium telluride (MCT) detector (Bruker Co.). Infrared spectra obtained using synchrotron IR beam with an aperture of 50 × 50 μm2, and 128 scans were measured in transmission mode while treating the background from the diamond signal using OPUS 7.5 software (Bruker Co.).
Large volume press experiments
Ex situ high-pressure and -temperature syntheses were performed using a QUICKpress apparatus (Depths of the Earth Co.) on a series of samples at various albite-to-water ratios from 50 wt.% down to 6 wt.% H2O using an analytical balance (Precisa XB 220A). Each albite and water mixture was loaded into a 3.4-mm diameter and 12-mm height Teflon capsule. A piston of 10 mm diameter and a cylindrical graphite heater were used to treat the sample at 2.4 GPa and 260 °C for 1 h. Each recovered product was identified using FE-SEM and XRD as described above (Fig. 3c and Supplementary Fig. 2).
A modified Griggs apparatus experiment and SEM-EDS measurement
The starting material was a natural basalt rock collected from Jeongok in Korea. The sample is massive and fine-grained containing plagioclase (~56 vol.%), alkali-feldspar (~10 vol.%), clinopyroxene (augite) (~10 vol.%), olivine (forsterite) (~23 vol.%), and ilmenite (~1 vol.%). The composition of feldspars was measured using the JEOL JXA-8530F field emission electron probe microanalyzer (FE-EPMA) at the National Center for Inter-university Research Facilities at Seoul National University (SNU), Korea. The measurement conditions included accelerating voltage of 15 kV, current of 10 nA, and beam size of 10 × 10 μm2. The derived chemical formula of feldspars was K0.02Na0.36Ca0.62Al1.60Si2.38O8 for plagioclase (labradorite), and K0.32Na0.58Ca0.04Al0.98Si2.88O8 for alkali-feldspar (sanidine). Using a modified Griggs apparatus42 housed at the Tectonophysics Laboratory at the School of Earth and Environmental Sciences (SEES) at SNU, a core-drilled basalt sample with 3 mm diameter was pressurized up to 2.5 GPa over 10 h and then heated up to 250 °C in 15 min, which was held for 10 h. The experiments were performed at dry and wet (5.5 wt.% H2O) conditions. A graphite heater was used, and temperature was monitored using a B-type thermocouple to the maximum uncertainties of ±10 °C. After the P-T run, the sample was quenched to room temperature. Field emission-scanning electron microscopy with energy dispersive spectroscopy (FE-SEM-EDS) measurement was carried out on the recovered core samples using the FE-SEM (JSM 7100F) and the EDS system (Oxford Instruments) at the SEES at SNU. Back-scattered electron images of the recovered samples were also obtained using the same FE-SEM (JSM 7100F), which was operated at an accelerating voltage of 15 kV and a working distance of 10 mm.
Calculation procedures of the “net crystalline density” and “net fluid volume”
Net crystalline density
Density of each phase was calculated using ρcalc (g cm−3) = (M Z V−1) × (Avogadro’s number)−1. V (Å3) is derived from profile fitting using the GSAS program43,44. M is the molecular weight and Z is the number of the formula unit per unit cell. Net crystalline density accounts the proportions of the composing crystalline phases. Net crystalline density is described here as:
where a, b, c, …, and z means the proportions of the composing crystalline phases. The calculated density of each phase, ρa, is derived from XRD data.
Net fluid volume
To determine the changes in the net fluid volume after the reaction, the initial volume of albite and water per mole is defined as:
Based on the reaction schemes of the hydration (1) and dehydration (2) breakdowns, changes in the net fluid volume are then calculated.
Data availability
All data generated or analyzed during this study are included with this published article and its Supplementary Information.
References
White, D. A., Roeder, D. H., Nelson, T. H. & Crowell, J. C. Subduction. Geol. Soc. Am. Bull. 81, 3431–3432 (1970).
Stern, R. J. Subduction zones. Rev. Geophys. 40, 3-1–3-38 (2002).
Galvez, M. E., Connolly, J. A. & Manning, C. E. Implications for metal and volatile cycles from the pH of subduction zone fluids. Nature 539, 420–424 (2016).
Stern, R. J. & Gerya, T. Subduction initiation in nature and models: a review. Tectonophysics 746, 173–198 (2018).
Grove, T. L., Till, C. B. & Krawczynski, M. J. The role of H2O in subduction zone magmatism. Annu. Rev. Earth. Planet. Sci. 40, 413–439 (2012).
Cervantes, P. & Wallace, P. J. Role of H2O in subduction-zone magmatism: new insights from melt inclusions in high-Mg basalts from central Mexico. Geology 31, 235–238 (2003).
Hacker, B. R., Peacock, S. M., Abers, G. A. & Holloway, S. D. Subduction factory 2. Are intermediate‐depth earthquakes in subducting slabs linked to metamorphic dehydration reactions? J. Geophys. Res. 108, 2030 (2003).
Hacker, B. R., Abers, G. A. & Peacock, S. M. Subduction factory 1. Theoretical mineralogy, densities, seismic wave speeds, and H2O contents. J. Geophys. Res. 108, 2029 (2003).
van Keken, P. E., Hacker, B. R., Syracuse, E. M. & Abers, G. A. Subduction factory: 4. Depth‐dependent flux of H2O from subducting slabs worldwide. J. Geophys. Res. 116, B01401 (2011).
Tatsumi, Y. & Kogiso, T. The subduction factory: its role in the evolution of the Earth’s crust and mantle. Geol. Soc. Spec. Publ. 219, 55–80 (2003).
Cai, C., Wiens, D. A., Shen, W. & Eimer, M. Water input into the Mariana subduction zone estimated from ocean-bottom seismic data. Nature 563, 389–392 (2018).
Borghini, G., Fumagalli, P. & Rampone, E. The stability of plagioclase in the upper mantle: subsolidus experiments on fertile and depleted lherzolite. J. Petrol. 51, 229–254 (2010).
Shen, A. H. & Keppler, H. Direct observation of complete miscibility in the albite–H2O system. Nature 385, 710–712 (1997).
Bennett, E. N., Jenner, F. E., Millet, M.-A., Cashman, K. V. & Lissenberg, C. J. Deep roots for mid-ocean-ridge volcanoes revealed by plagioclase-hosted melt inclusions. Nature 572, 235–239 (2019).
Birch, A. F. & LeComte, P. Temperature-pressure plane for albite composition. Am. J. Sci. 258, 209–217 (1960).
Holland, T. J. The reaction albite = jadeite + quartz determined experimentally in the range 600–1200 °C. Am. Mineral. 65, 129–134 (1980).
Peacock, S. M. Thermal Structure and Metamorphic Evolution of Subducting Slabs. in Inside the Subduction Factory. (ed. Eiler, J.) 7–22 (American Geophysical Union, 2003).
van Keken, P. E., Kiefer, B. & Peacock, S. M. High‐resolution models of subduction zones: Implications for mineral dehydration reactions and the transport of water into the deep mantle. Geochem. Geophys. Geosyst. 3, 1–20 (2002).
Hacker, B. R. H2O subduction beyond arcs. Geochem. Geophys. Geosyst. 9, Q03001 (2008).
Syracuse, E. M., van Keken, P. E. & Abers, G. A. The global range of subduction zone thermal models. Phys. Earth Planet. Inter. 183, 73–90 (2010).
Ferrage, E. Investigation of the interlayer organization of water and ions in smectite from the combined use of diffraction experiments and molecular simulations. A review of methodology, applications, and perspectives. Clays Clay Miner. 64, 348–373 (2016).
Meunier, A. Clays Vol. 1, 472 (Springer, 2005).
Kayama, M. et al. Discovery of moganite in a lunar meteorite as a trace of H2O ice in the Moon’s regolith. Sci. Adv. 4, 1–11 (2018).
Cama, J., Ganor, J., Ayora, C. & Lasaga, C. A. Smectite dissolution kinetics at 80 °C and pH 8.8. Geochim. Cosmochim. Acta 64, 2701–2717 (2000).
Mookherjee, M. et al. Pressure induced elastic softening in framework aluminosilicate-albite (NaAlSi3O8). Sci. Rep. 6, 1–10 (2016).
Carl, E.-R. et al. High-pressure phase transitions of α-quartz under nonhydrostatic dynamic conditions: A reconnaissance study at PETRA III. Meteorit. Planet. Sci. 52, 1465–1474 (2017).
Krobok, M., Johannsen, P. & Holzapfel, W. Raman and FTIR study of NaOH and NaOD under pressure. J. Phys. Condens. Matter 4, 8141 (1992).
Kloprogge, J. T. Spectroscopic studies of synthetic and natural beidellites: a review. Appl. Clay Sci. 31, 165–179 (2006).
Briggs, R., Utting, A. & Gibson, I. The origin of alkaline magmas in an intraplate setting near a subduction zone: the Ngatutura Basalts, North Island, New Zealand. J. Volcanol. Geotherm. Res. 40, 55–70 (1990).
Schmidt, M. W. & Poli, S. Treatise on Geochemistry (Second Edition): Devolatilization During Subduction Vol. 4, 669–701 (Elsevier, 2013).
Zheng, Y., Chen, R., Xu, Z. & Zhang, S. The transport of water in subduction zones. Sci. China Earth Sci. 59, 651–682 (2016).
Faccenda, M. Water in the slab: a trilogy. Tectonophysics 614, 1–30 (2014).
Ikari, M. J. & Kopf, A. J. Seismic potential of weak, near-surface faults revealed at plate tectonic slip rates. Sci. Adv. 3, e1701269 (2017).
Hirono, T., Tsuda, K. & Kaneki, S. Role of weak materials in earthquake rupture dynamics. Sci. Rep. 9, 6604 (2019).
Jung, H., Green, Ii,H. W. & Dobrzhinetskaya, L. F. Intermediate-depth earthquake faulting by dehydration embrittlement with negative volume change. Nature 428, 545–549 (2004).
Zheng, Y.-F. Subduction zone geochemistry. Geosci. Front. 10, 1223–1254 (2019).
McMillan, P. F. Water solubility and speciation models. in Volatiles in magmas. (eds Carroll, M. R. & Holloway, J. R.) 131–156 (Mineralogical Society of America, 1994).
Pommier, A. Geophysical assessment of migration and storage conditions of fluids in subduction zones. Earth Planets Space 66, 38 (2014).
Ni, H., Keppler, H. & Behrens, H. Electrical conductivity of hydrous basaltic melts: implications for partial melting in the upper mantle. Contrib. Mineral. Petrol. 162, 637–650 (2011).
Jenei, Z., Cynn, H., Visbeck, K. & Evans, W. J. High-temperature experiments using a resistively heated high-pressure membrane diamond anvil cell. Rev. Sci. Instrum. 84, 095114 (2013).
Méndez, A. S. J. et al. A resistively-heated dynamic diamond anvil cell (RHdDAC) for fast compression x-ray diffraction experiments at high temperatures. Rev. Sci. Instrum. 91, 073906 (2020).
Ko, B. & Jung, H. Crystal preferred orientation of an amphibole experimentally deformed by simple shear. Nat. Commun. 6, 1–10 (2015).
Le Bail, A., Duroy, H. & Fourquet, J. L. Ab-initio structure determination of LiSbWO6 by X-ray powder diffraction. Mater. Res. Bull. 23, 447–452 (1988).
Toby, B. EXPGUI, a graphical user interface for GSAS. J. Appl. Crystallogr. 34, 210–213 (2001).
Harlow, G. E. The anorthoclase structures: the effects of temperature and composition. Am. Mineral. 67, 975–996 (1982).
Weir, A. H. & Greene-Kelly, R. Beidellite. Am. Mineral. 47, 137–146 (1962).
Gournis, D., Lappas, A., Karakassides, M. A., Többens, D. & Moukarika, A. A neutron diffraction study of alkali cation migration in montmorillonites. Phys. Chem. Miner. 35, 49–58 (2008).
Prewitt, C. & Burnham, C. W. The crystal structure of jadeite, NaAlSi2O6. Am. Mineral. 51, 956–975 (1966).
Miehe, G. & Graetsch, H. Crystal structure of moganite: a new structure type for silica. Eur. J. Mineral. 4, 693–706 (1992).
Newnham, R. & De Haan, Y. Refinement of the α Al2O3, Ti2O3, V2O3 and Cr2O3 structures. Z. Kristallogr. Cryst. Mater. 117, 235–237 (1962).
Anderson, O. L., Isaak, D. G. & Yamamoto, S. Anharmonicity and the equation of state for gold. J. Appl. Phys. 65, 1534–1543 (1989).
Wang, Y. et al. Thermal equation of state of copper studied by high P-T synchrotron x-ray diffraction. Appl. Phys. Lett. 94, 071904 (2009).
Acknowledgements
This work was supported by the Leader Researcher program (NRF-2018R1A3B1052042) of the Korean Ministry of Science, ICT and Planning (MSIP). We also thank the support of the NRF-2016K1A4A3914691, NRF-2019K1A3A7A09033395, and NRF-2020R1A2C2003765. Experiments using synchrotron radiation were supported by Pohang Accelerator Laboratory (PAL).
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G.H., H.H., and Y.B. contributed equally to the experiments and data analysis with the help from J.C., T.J., and B.C. Y.P. and H.J. contributed to the modified Griggs apparatus experiment. Y.L. designed the research and worked on the manuscript with all authors.
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Hwang, G.C., Hwang, H., Bang, Y. et al. A role for subducted albite in the water cycle and alkalinity of subduction fluids. Nat Commun 12, 1155 (2021). https://doi.org/10.1038/s41467-021-21419-6
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DOI: https://doi.org/10.1038/s41467-021-21419-6
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