Featured
-
-
Article |
Catalytic subsurface etching of nanoscale channels in graphite
Metallic particles are known to etch the surface layers of graphite by catalytic hydrogenation. Here, the authors report the sub-surface etching of graphite by Ni nanoparticles, revealing the formation of networks of tunnels, which are observed microscopically and could be modified for various applications.
- Maya Lukas
- , Velimir Meded
- & Ralph Krupke
-
Article |
Removal of stacking-fault tetrahedra by twin boundaries in nanotwinned metals
The bombardment of structural metals in nuclear reactors by high-energy particles causes them to develop defects, such as stacking-fault tetrahedra defects, that are difficult to cure. Yu et al.find that in nanotwinned silver such defects can be removed at room temperature by the propagation of mobile twin boundaries.
- K. Y. Yu
- , D. Bufford
- & X. Zhang
-
Article |
A high-mobility two-dimensional electron gas at the spinel/perovskite interface of γ-Al2O3/SrTiO3
Highly mobile electrons at the interface of two perovskite oxides are of considerable interest for electronic applications. In this work, the discovery of such an electron gas at the interface of a spinel and a perovskite oxide represents a new approach to look for oxide systems with enhanced properties.
- Y. Z. Chen
- , N. Bovet
- & N. Pryds
-
Article |
Observation of a large spin-dependent transport length in organic spin valves at room temperature
Spin-dependent transport length in organic semiconductors is expected to be large due to their small spin–orbit coupling; however, lengths of only a few nanometres have been observed to date at room temperature. This work reports a large spin diffusion length of 110 nm at room temperature in a spin valve device containing C60molecules.
- Xianmin Zhang
- , Shigemi Mizukami
- & Terunobu Miyazaki
-
Article
| Open AccessStrain-controlled magnetic domain wall propagation in hybrid piezoelectric/ferromagnetic structures
The use of electric fields to control the magnetization of ferromagnetic materials could enable more efficient electronics. Lei et al.show that by applying lateral strain to a magnetostrictive nanowire with a piezoelectric, voltage-controlled gating of magnetic domain wall motion in the wire can be achieved.
- Na Lei
- , Thibaut Devolder
- & Philippe Lecoeur
-
Article |
Creation of helical Dirac fermions by interfacing two gapped systems of ordinary fermions
Helical Dirac fermion states that emerge at the surface of topological insulators support a variety of exotic physical phenomena, but they disappear when a topological insulator becomes too thin. Wang et al.show that these states are recovered when ultrathin films are interfaced together.
- Z. F. Wang
- , Meng-Yu Yao
- & Feng Liu
-
Article |
The mechanism of ultrafast structural switching in superionic copper (I) sulphide nanocrystals
Superionic materials have rigid crystal structures but liquid-like ionic conductivity above a critical temperature, which may be useful for switching and storage applications. Using ultrafast X-ray probes, Miller et al.show that the superionic transition timescale is determined by the ionic hopping time.
- T. A. Miller
- , J. S. Wittenberg
- & A. M. Lindenberg
-
Article |
The random mass Dirac model and long-range correlations on an integrated optical platform
Photonic lattices provide a useful platform for simulating quantum dynamics and systems. Keil et al.fabricate coupled waveguides on-chip and use them to simulate the one-dimensional random mass Dirac model, a test-bed for both Dirac fermions and antiferromagnetic spin systems.
- Robert Keil
- , Julia M. Zeuner
- & Alexander Szameit
-
Article
| Open AccessVisualization and quantification of transition metal atomic mixing in Mo1−xWxS2 single layers
Understanding the influence of disorder on the properties of two-dimensional materials is of increasing importance, given the interest in these compounds for electronic applications. Using a scanning transmission electron microscope, Dumcencoet al. quantify the atomic mixing in two-dimensional films of Mo1–xWxS2.
- Dumitru O Dumcenco
- , Haruka Kobayashi
- & Kazu Suenaga
-
Article
| Open AccessPlasmon transport in graphene investigated by time-resolved electrical measurements
In metals, plasmon properties are fixed once the structure is built, but in graphene they can be altered by electric or magnetic fields. Using electrical time-of-flight measurements, Kumada et al. show wide plasmon velocity tunability in graphene with a varying magnetic field.
- N. Kumada
- , S. Tanabe
- & T. Fujisawa
-
Article |
Unprecedented high-temperature CO2 selectivity in N2-phobic nanoporous covalent organic polymers
Porous materials are well studied for gas capture and separation technologies. Here, the authors report nitrogen-rich, nanoporous polymers, which display very high CO2/N2 selectivity with increasing temperature, which may be attributable to an entropically driven N2-phobicity effect.
- Hasmukh A. Patel
- , Sang Hyun Je
- & Ali Coskun
-
Article |
Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries
The practical performance of lithium–sulphur batteries is lower than expected because of polysulphide dissolution into the electrolyte over time. Sehet al. show that a yolk–shell nanoarchitecture is able to encapsulate sulphur cathode materials efficiently and thus allows over 1,000 charge/discharge cycles.
- Zhi Wei Seh
- , Weiyang Li
- & Yi Cui
-
Article |
Blood-clotting-inspired reversible polymer–colloid composite assembly in flow
Blood clotting is caused by biopolymer-mediated aggregation of platelets and is enhanced by fast shear flows. Chen et al. find a similar process that arises during the self-assembly of polymer–colloid composites—a process that can be controlled and even reversed by flow rate and interparticle interaction.
- Hsieh Chen
- , Mohammad A. Fallah
- & Alfredo Alexander-Katz
-
Article |
High current superconductivity in FeSe0.5Te0.5-coated conductors at 30 tesla
Iron-based superconductors have the potential to carry higher currents and withstand higher magnetic fields than present-day superconducting cables. Using an approach developed for cuprates, Si et al. improve the high-field performance of iron-based superconductors well beyond that of conventional superconductors.
- Weidong Si
- , Su Jung Han
- & Qiang Li
-
Article |
Probing the electronic structure at semiconductor surfaces using charge transport in nanomembranes
As the electrical properties of nanostructures are strongly influenced by their surface, a thorough understanding of the surface properties is desirable. The authors demonstrate the use of charge transport in silicon nanomembranes to perform spectroscopy of the electronic structure of the surface states.
- Weina Peng
- , Zlatan Aksamija
- & Max G. Lagally
-
Article |
Hydrogen bond-promoted metallic state in a purely organic single-component conductor under pressure
Purely organic materials are generally insulating and while charge-carrier generation can provide electrical conductivity, it is rare for single-component systems. Here, symmetric hydrogen bonding between tetrathiafulvalene-based molecules gives rise to room-temperature conductivity and low pressure metallic state transitions.
- Takayuki Isono
- , Hiromichi Kamo
- & Hatsumi Mori
-
Article |
Reversible control of magnetic interactions by electric field in a single-phase material
The ability to control the magnetic order in a material with an electric field will enable low-power non-volatile memories and new types of computer logic. Ryanet al. demonstrate that europium titanate under moderate strain exhibits strong magnetoelectric coupling that could be valuable to this endeavour.
- P. J. Ryan
- , J-W Kim
- & D. G. Schlom
-
Article |
Exotic non-Abelian anyons from conventional fractional quantum Hall states
Non-Abelian anyons are exotic quasiparticles envisioned to be promising candidates for solid-state quantum computation. Clarkeet al. propose a device fabricated from fractional quantum Hall states and superconductors that supports a new type of non-Abelian defect that binds parafermionic zero modes.
- David J. Clarke
- , Jason Alicea
- & Kirill Shtengel
-
Article |
From chaos to selective ordering of vortex cores in interacting mesomagnets
The collective gyrotropic excitation of an array of spin vortices has frequencies that depend on the polarities and chirality of individual vortices. This work demonstrates control of the spectral response of the system by tuning the excitation frequency or the external magnetic field.
- S. Jain
- , V. Novosad
- & S.D. Bader
-
Article
| Open AccessAtomic-scale engineering of magnetic anisotropy of nanostructures through interfaces and interlines
The design and assembly of nanostructures exhibiting ferromagnetic hysteresis at room temperature are recognized goals for high-density data storage. Here, the authors engineer nanostructures with atomically sharp bimetallic interfaces and interlines, which exhibit large magnetic anisotropy and high temperature hysteresis.
- S. Ouazi
- , S. Vlaic
- & H. Brune
-
Article
| Open AccessHigh internal quantum efficiency in fullerene solar cells based on crosslinked polymer donor networks
The conversion efficiency of organic solar cells depends on the shape of the interface between their donor and acceptor components. Liuet al. demonstrate a scalable method using crosslinked polymer networks to fabricate the finely interpenetrating structures needed to achieve near-perfect internal quantum efficiency.
- Bo Liu
- , Rui-Qi Png
- & Peter K.H. Ho
-
Article |
Extracting net current from an upstream neutral mode in the fractional quantum Hall regime
One of the many exotic characteristics of systems that exhibit the fractional quantum Hall effect is the presence of chiral edge modes that carry energy but no net charge. Gurman et al.demonstrate the use of quantum dots to transform this energy into a measurable current, enabling them to better probe these modes.
- I. Gurman
- , R. Sabo
- & D. Mahalu
-
Article
| Open AccessBolaform surfactants with polyoxometalate head groups and their assembly into ultra-small monolayer membrane vesicles
Bolaform amphiphiles are surfactants with two hydrophilic end groups, known to form stable micelles. Polarz et al.have synthesized dipolar bolaform surfactants with polyoxometallate head groups, which have a very low self-organization concentration and form nanoscale monolayer vesicles.
- Steve Landsmann
- , Martin Luka
- & Sebastian Polarz
-
Article |
Magneto-optical properties of trions in non-blinking charged nanocrystals reveal an acoustic phonon bottleneck
Colloidal quantum dots may be used in a variety of emerging technologies, particularly if charged states can be stabilized. Here, cadmium selenide core-shell nanocrystals are engineered for trion emission at low temperatures, and their finite size introduces an acoustic phonon bottleneck, inhibiting spin relaxation.
- Mark J. Fernée
- , Chiara Sinito
- & Brahim Lounis
-
Article
| Open AccessModulation-doped growth of mosaic graphene with single-crystalline p–n junctions for efficient photocurrent generation
Combination of p- and n-doped graphene is important in optoelectronic applications, but spatially selective doping of graphene is challenging. This work reports large-scale growth of graphene monolayers with spatially modulation doping and built-in single-crystalline p–n junctions.
- Kai Yan
- , Di Wu
- & Zhongfan Liu
-
Review Article |
Moving from static to dynamic complexity in hydrogel design
Hydrogels are water-containing polymer networks that have been applied in various biological settings. Burdick and Murphy review recent advances in the development of dynamic hydrogels whose properties and mechanics change in response to biological signals.
- Jason A. Burdick
- & William L. Murphy
-
Article
| Open AccessMicroelectromechanical Maltese-cross metamaterial with tunable terahertz anisotropy
Metamaterials can be designed with anisotropy, which tailors their optical properties to enable interesting functionalities. Here, the anisotropy of a Maltese-cross metamaterial is actively controlled by an actuator, allowing for tunable birefringence and dichroism in the terahertz frequency region.
- W.M. Zhu
- , A.Q. Liu
- & N.I. Zheludev
-
Article |
Holographic detection of the orbital angular momentum of light with plasmonic photodiodes
Sub-wavelength structures can be used to convert between light and plasmon polaritons. Genevetet al. design holographic plasmonic interfaces that couple vortex light beams to surface plasmons, allowing them to detect the orbital angular momentum of the beam with a simple silicon photodiode.
- Patrice Genevet
- , Jiao Lin
- & Federico Capasso
-
Article
| Open AccessExpansion–contraction of photoresponsive artificial muscle regulated by host–guest interactions
Polymer-based actuators, which deform in response to external stimuli, may advance the understanding of biological movement or realization of soft robotics. Here, Harada et al. report a photo-responsive supramolecular hydrogel that displays expansion–contraction abilities owing to host–guest interactions.
- Yoshinori Takashima
- , Shogo Hatanaka
- & Akira Harada
-
Article |
Magneto-orbital helices as a route to coupling magnetism and ferroelectricity in multiferroic CaMn7O12
The coupling of magnetism and ferroelectricity is of relevance for applications such as sensing, but occurs only rarely in bulk materials. The large magnetically induced ferroelectric polarization observed here in CaMn7O12establishes a new approach to achieve a strong magnetoelectric coupling.
- N.J. Perks
- , R.D. Johnson
- & P.G. Radaelli
-
Article |
Growth and optical properties of axial hybrid III–V/silicon nanowires
Nanowires with sharp interfaces between two different semiconducting materials could lead to useful nanoelectronic and nanophotonic structures. Hocevar et al.develop a method to integrate a gallium arsenide section in silicon nanowires with atomically sharp interfaces and no dislocations.
- Moïra Hocevar
- , George Immink
- & Erik Bakkers
-
Article |
The surface plasmon modes of self-assembled gold nanocrystals
The 3D self-assembly of nanocrystals could generate materials with unique optical and electronic properties. Barrowet al. report the DNA-mediated assembly of symmetrical 3D gold tetrahedra, pentamers and hexamers, and elucidate their plasmon modes.
- Steven J. Barrow
- , Xingzhan Wei
- & Paul Mulvaney
-
Article |
Ultra-flexible solution-processed organic field-effect transistors
Organic electronic materials are promising candidates for applications in which flexible electronic devices are required. Yiet al. demonstrate a high-performance, flexible organic transistor based on solution-processed small molecules that can be fabricated with a simple, low-cost process.
- Hee Taek Yi
- , Marcia M. Payne
- & Vitaly Podzorov
-
Article |
Single-particle structure determination by correlations of snapshot X-ray diffraction patterns
Free-electron lasers enable diffractive imaging of single nanostructures, but algorithms, such as correlation analyses, are needed to determine their diffraction volume from accumulated data. Starodub et al.present such a method for X-ray diffractive imaging of nanometre-scale polystyrene dimers.
- D. Starodub
- , A. Aquila
- & M.J. Bogan
-
Article |
Stretchable heterogeneous composites with extreme mechanical gradients
Heterogeneous composite materials, which are potentially useful for flexible electronics, are widespread in nature but synthetic examples are rare. Here, a site-specific hierarchical approach is used to fabricate composites with extreme local variations in elastic modulus and which are reversibly stretchable.
- Rafael Libanori
- , Randall M. Erb
- & André R. Studart
-
Article |
Quantum and classical confinement of resonant states in a trilayer graphene Fabry-Pérot interferometer
Multilayer graphene is a promising electronic material because of its tunable band structure and pseudospin properties. Campos et al.show giant conductance oscillations in a ballistic trilayer graphene Fabry-Pérot interferometer that can be suppressed both classically and quantum mechanically.
- L.C. Campos
- , A.F. Young
- & P. Jarillo-Herrero
-
Article |
Water tribology on graphene
The frictional force required to move a liquid drop on a surface is known to depend upon the drop resting time. N'guessan et al. demonstrate that water drops on graphene surfaces are an exception, which is attributable to the chemical homogeneity and stability of graphene surfaces.
- Hartmann E. N’guessan
- , Aisha Leh
- & Priyanka Wasnik
-
Article |
Geometrically locked vortex lattices in semiconductor quantum fluids
Polariton condensates provide an arena in which to study interesting non-equilibrium condensate dynamics. Tosi et al. generate stable vortex lattices in a polariton condensate and study their macroscopic wavefunction, uncovering a nonlinear regime for topological defects at high densities.
- G. Tosi
- , G. Christmann
- & J.J. Baumberg
-
Article |
Supercooled liquids with enhanced orientational order
Medium-range structural ordering is expected to exist in supercooled liquids yet direct probes of this are difficult to achieve. Capponi et al.report a new metastable phase of organic molecular glasses exhibiting long-living, highly enhanced orientational order above its glass transition temperature.
- Simona Capponi
- , Simone Napolitano
- & Michael Wübbenhorst
-
Article |
A seamless three-dimensional carbon nanotube graphene hybrid material
Graphene and single-walled carbon nanotubes have high electrical conductivities and large specific surface areas. Here, these properties are extended into three dimensions by producing a seamless carbon nanotube graphene hybrid material.
- Yu Zhu
- , Lei Li
- & James M. Tour
-
Article |
Giant Rashba splitting in graphene due to hybridization with gold
The potential use of graphene in spintronic devices is limited by its weak spin–orbit coupling. Marchenko et al. report an enhancement of the spin splitting in graphene due to hybridization with gold 5dorbitals, showing a very large Rashba spin–orbit splitting of about 100 meV.
- D. Marchenko
- , A. Varykhalov
- & O. Rader
-
Article |
Driving diffusionless transformations in colloidal crystals using DNA handshaking
Crystalline material may be stabilized by complementary DNA interactions but its subsequent capacity for structural transformation is poorly understood. Here, by tuning the DNA handshaking between two sets of nanoparticles, a Martensitic transformation within the binary colloidal crystals is observed.
- Marie T. Casey
- , Raynaldo T. Scarlett
- & John C. Crocker
-
Article
| Open AccessSynthesis of chiral TiO2 nanofibre with electron transition-based optical activity
Optical activity resulting from electronic transitions in chiral inorganic materials is rare. Liu et al. report the synthesis of amino acid-derived amphiphile templated chiral TiO2fibres, which exhibit an optical response to polarized light resulting from valence to conduction band electronic transitions.
- Shaohua Liu
- , Lu Han
- & Shunai Che
-
Article |
Flexible and low-voltage integrated circuits constructed from high-performance nanocrystal transistors
Field-effect transistors based on semiconductor nanocrystals are promising candidates for low-cost, flexible electronics. This work demonstrates fabrication on flexible substrates and low-voltage operations of integrated circuits based on nanocrystal transistors, including amplifiers and ring oscillators.
- David K. Kim
- , Yuming Lai
- & Cherie R. Kagan
-
Article |
Hopping transport and the Hall effect near the insulator–metal transition in electrochemically gated poly(3-hexylthiophene) transistors
Understanding charge transport and the fundamental limits on conductivity in polymer semiconductors is important for improving device performance. Wanget al. report a transport regime close to band-like conduction and the observation of the Hall effect in an electrochemically-doped polymer semiconductor.
- Shun Wang
- , Mingjing Ha
- & C Leighton
-
Article |
Broadband electromagnetic cloaking with smart metamaterials
Metamaterial cloaks can manipulate light to effectively hide objects from view, but they mostly rely on rigid structures that are tailored specifically for the chosen object. Shin et al.demonstrate an elastic, smart metamaterial cloak that can adapt to a range of deformations and object sizes.
- Dongheok Shin
- , Yaroslav Urzhumov
- & David R. Smith
-
Article |
Room temperature self-assembly of mixed nanoparticles into photonic structures
Integration of different compounds with silica is important for developing small-scale optical devices, yet the high temperatures needed to build silica waveguides impose limits. Here, a room-temperature, self-assembly approach is shown, which produces long microwires containing nanodiamonds or organic dyes.
- Masood Naqshbandi
- , John Canning
- & Maxwell J. Crossley
-
Article
| Open AccessDirect writing of electronic devices on graphene oxide by catalytic scanning probe lithography
Controlled nanoscale reduction of graphene oxide could aid the development of graphene-based electronics. Here, a relatively mild technique is reported that uses a platinum-coated atomic force microscope tip to catalyse the reduction of graphene oxide to graphene.
- Kun Zhang
- , Qiang Fu
- & Jianguo Hou
-
Article
| Open AccessControl of exciton spin statistics through spin polarization in organic optoelectronic devices
Control of spin statistics by spin injection from ferromagnetic electrodes has been shown to achieve only weak effects in organic optoelectronic devices. Wang et al.use instead polarization of spins after injection, at high magnetic fields and low temperatures, achieving a 50% change in device characteristics.
- Jianpu Wang
- , Alexei Chepelianskii
- & Neil C. Greenham