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| Open AccessOptimization of the structural characteristics of CaO and its effective stabilization yield high-capacity CO2 sorbents
The economic operation of a carbon dioxide capture technique of calcium looping necessitates highly effective CaO-based CO2 sorbents. Here, the authors report a facile one-pot synthesis approach to yield highly effective, MgO-stabilized, CaO-based CO2 sorbents featuring highly porous multishelled morphologies.
- Muhammad Awais Naeem
- , Andac Armutlulu
- & Christoph R. Müller
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Article
| Open AccessCoherent exciton-vibrational dynamics and energy transfer in conjugated organics
Interference patterns in photoexcited dynamics of many materials have historically been attributed to electronic and vibrational coherences. Here, the authors demonstrate a simple model based on wavefunction symmetry suggesting these coherences originate from non-adiabatic transitions for optically active molecules.
- Tammie R. Nelson
- , Dianelys Ondarse-Alvarez
- & Sergei Tretiak
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Article
| Open AccessEstimating geological CO2 storage security to deliver on climate mitigation
Carbon capture and storage can help reduce CO2 emissions but the confidence in geologic CO2 storage security is uncertain. Here the authors present a numerical programme to estimate leakage from wells and find that under appropriate regulation 98% of injected CO2 will be retained over 10,000 years.
- Juan Alcalde
- , Stephanie Flude
- & R. Stuart Haszeldine
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Article
| Open AccessNanoscale membranes that chemically isolate and electronically wire up the abiotic/biotic interface
Bioelectrochemical cells have huge potential, yet incompatibilities between the microbe and abiotic catalysts can affect efficiency. Here, the authors report the development of thin silica membranes with bridging molecular wires that chemically separate yet electrically connect the two components.
- Jose A. Cornejo
- , Hua Sheng
- & Heinz Frei
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Article
| Open AccessSolvent-controlled growth of inorganic perovskite films in dry environment for efficient and stable solar cells
Cesium lead iodide inorganic perovskite solar cells have great potential but the phase instability hinders their development. Here Wang et al. show a controlled drying process to make phase stable and highly efficient solar cells with power conversion efficiency of 15.7%.
- Pengyang Wang
- , Xingwang Zhang
- & Jingbi You
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Article
| Open AccessVapor transport deposition of antimony selenide thin film solar cells with 7.6% efficiency
Antimony selenide possess several advantages for solar cell applications but state-of-the-art vapor transport deposition methods suffer from poor film quality. Here Wen et al. develop a fast and cheap method to reduce the defect density by 10 times and achieve a certified power conversion efficiency of 7.6%.
- Xixing Wen
- , Chao Chen
- & Jiang Tang
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Article
| Open AccessLive cyanobacteria produce photocurrent and hydrogen using both the respiratory and photosynthetic systems
Biologically ### produced electrical currents and hydrogen are new energy sources. Here, the authors find that low presser microfluidizer treatment produced cyanobacterium that can utilize electrons from respiratory and photosynthesis to promote current and hydrogen generation, without the addition of exogenous electron mediators.
- Gadiel Saper
- , Dan Kallmann
- & Noam Adir
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Article
| Open AccessOperando monitoring the lithium spatial distribution of lithium metal anodes
Rechargeable lithium metal batteries could offer a major leap in energy capacity but suffer from the electrolyte reactivity and dendrite growth. Here the authors apply neutron depth profiling to provide quantitative insight into the evolution of the Li-metal morphology during plating and stripping.
- Shasha Lv
- , Tomas Verhallen
- & Marnix Wagemaker
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Article
| Open AccessRobust nonfullerene solar cells approaching unity external quantum efficiency enabled by suppression of geminate recombination
The nonfullerene-based small molecules start to attract more attention for solar cell research than the fullerene acceptors due to their wider tunability. Here Baran et al. demonstrate nonfullerene-based solar cells with high power conversion efficiency of 12% and quantum efficiencies approaching 100%.
- Derya Baran
- , Nicola Gasparini
- & Iain McCulloch
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Article
| Open AccessProbing the pathways of free charge generation in organic bulk heterojunction solar cells
Contradictory models are being debated on the dominant pathways of charge generation in organic solar cells. Here Kurpiers et al. determine the activation energy for this fundamental process and reveal that the main channel is via thermalized charge transfer states instead of hot exciton dissociation.
- Jona Kurpiers
- , Thomas Ferron
- & Dieter Neher
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Article
| Open AccessProbing femtosecond lattice displacement upon photo-carrier generation in lead halide perovskite
The electron–phonon coupling is the key to understand optoelectronic properties in lead halide perovskites but it is difficult to probe. Here Batignani et al. observe two new phonon modes with impulsive vibrational spectroscopy providing the evidence of the polaronic nature of the photo-excitation.
- Giovanni Batignani
- , Giuseppe Fumero
- & Tullio Scopigno
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Article
| Open AccessDynamically induced cascading failures in power grids
Communication networks and power grids may be subject to cascading failures which can lead to outages. Here the authors propose to investigate cascades using dynamical transients of electrical power grids, thereby identifying possible vulnerabilities that might remain undetected with any static approach.
- Benjamin Schäfer
- , Dirk Witthaut
- & Vito Latora
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| Open AccessGiant energy density and high efficiency achieved in bismuth ferrite-based film capacitors via domain engineering
Dielectrics with high capacitive energy storage density are essential for modern electrical devices and pulsed power systems. Here, the authors realised superior energy storage performance in lead-free bismuth ferrite-based relaxor ferroelectric films through domain engineering.
- Hao Pan
- , Jing Ma
- & Ce-Wen Nan
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Article
| Open AccessEnhanced electrocaloric efficiency via energy recovery
Electrocaloric materials can be electrically driven to pump heat and hold promise for use in efficient solid-state refrigeration. Here, the authors demonstrate an approach to recycle recoverable energy from electrocaloric cycles, offering a method to enhance performance in electrocaloric refrigeration systems.
- E. Defay
- , R. Faye
- & N. D. Mathur
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Article
| Open AccessTransparent and attachable ionic communicators based on self-cleanable triboelectric nanogenerators
Flexible, transparent wearable electronics harvesting energy from human motion are nearing reality, but stable adhesion while staying clean remains a problem. Here the authors solve both issues with a functionalized organic polymer/hydrogel-based device capable of wireless communication via finger gestures.
- Younghoon Lee
- , Seung Hee Cha
- & Jeong-Yun Sun
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| Open AccessA photochemical diode artificial photosynthesis system for unassisted high efficiency overall pure water splitting
A major challenge facing solar-to-fuel technologies is the integration of light-absorbing and catalytic components into efficient water-splitting devices. Here, the authors construct a photochemical diode array to harvest visible light and split pure water at high solar-to-hydrogen efficiencies.
- Faqrul A. Chowdhury
- , Michel L. Trudeau
- & Zetian Mi
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Article
| Open AccessAqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers
Rechargeable zinc-ion batteries are promising energy storage devices but suffer from the limited choice of positive electrodes. Here Niu and co-workers show a design with sodium vanadate hydrate as cathode, allowing simultaneous proton and zinc-ion insertion/extraction and enhanced performance.
- Fang Wan
- , Linlin Zhang
- & Jun Chen
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| Open AccessStrain-engineered inverse charge-funnelling in layered semiconductors
The application of strain to semiconducting materials can be used to engineer electric fields through a varying energy gap. Here, the authors observe an inverse charge-funnel effect in atomically thin HfS2, enabled by strain-induced electric fields.
- Adolfo De Sanctis
- , Iddo Amit
- & Saverio Russo
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Article
| Open AccessBio-inspired nano-traps for uranium extraction from seawater and recovery from nuclear waste
Uranium extraction is important for both uranium recovery and nuclear waste management. Here, inspired by the high sensitivity of proteins towards specific metal ions, Ma and colleagues demonstrate that introducing secondary coordination spheres into amidoxime-functionalized porous polymers can enhance their uranyl chelating abilities.
- Qi Sun
- , Briana Aguila
- & Shengqian Ma
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| Open AccessMolecular doping enabled scalable blading of efficient hole-transport-layer-free perovskite solar cells
The existing hole-transporting materials cause problems in the cost and scalability of the perovskite solar cells. Here Wu et al. fabricate high efficiency cells by molecularly doping the perovskite layer without using hole-transporting layers, thus simplify the device architecture and processing steps.
- Wu-Qiang Wu
- , Qi Wang
- & Jinsong Huang
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Article
| Open AccessElectron density modulation of NiCo2S4 nanowires by nitrogen incorporation for highly efficient hydrogen evolution catalysis
The hydrogen evolution reaction is a promising route to produce clean hydrogen fuel; however, its efficient electrolytic generation relies on expensive platinum. Here, the authors show how modulating electron density in a metal sulfide, NiCo2S4, boosts hydrogen desorption to achieve high catalytic activity.
- Yishang Wu
- , Xiaojing Liu
- & Gongming Wang
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Article
| Open AccessEnergy-loss return gate via liquid dielectric polarization
One major energy loss in electronics is heat dissipation due to induced polarization in dielectric materials in the presence of electric fields. Kim et al. utilize large polarization in liquids to harvest dielectric loss via an energy-loss return gate design, which converts energy back to electricity.
- Taehun Kim
- , Hyungseok Yong
- & Sangmin Lee
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Article
| Open AccessRETRACTED ARTICLE: Supported black phosphorus nanosheets as hydrogen-evolving photocatalyst achieving 5.4% energy conversion efficiency at 353 K
In order to displace fossil fuel technologies, it is crucial to develop efficient solar-to-fuel conversion materials using abundant, cheap elements. Here, the authors prepare few-layer black phosphorous with amorphous cobalt phosphide and produce hydrogen gas with light at high efficiencies.
- Bin Tian
- , Bining Tian
- & Yue Tian
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Article
| Open AccessExtraordinary pseudocapacitive energy storage triggered by phase transformation in hierarchical vanadium oxides
Pseudocapacitive materials could enable high-performance electrochemical supercapacitors, but their practical capacitance and power density remain low. Here the authors show that in situ phase transformation triggers extraordinary pseudocapacitive energy storage in metallic isomeric vanadium oxides.
- Bo-Tian Liu
- , Xiang-Mei Shi
- & Qing Jiang
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Article
| Open AccessDesignable ultra-smooth ultra-thin solid-electrolyte interphases of three alkali metal anodes
The dendrite growth of alkali metal anodes leads to charge/discharge cycling instability. Here, the authors show that electrochemical polishing can yield near-perfect anodes of three alkali metals by constructing smooth and thin solid-electrolyte interphase layers.
- Yu Gu
- , Wei-Wei Wang
- & Bing-Wei Mao
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Article
| Open AccessPorous translucent electrodes enhance current generation from photosynthetic biofilms
Some microorganisms are able to generate electrons that can be externally harvested. Here the authors show an increase by two orders of magnitude in the photocurrent when two cyanobacterial strains are grown on nanopourous transparent conducting substrates, compared to traditional solid substrates.
- Tobias Wenzel
- , Daniel Härtter
- & Ullrich Steiner
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Article
| Open AccessNuclear disarmament verification via resonant phenomena
Authenticating a nuclear warhead without revealing its design is a challenge. Here the authors discuss a nuclear disarmament verification method based on neutron resonance analysis which is sensitive to the isotopic composition of the materials used in warheads.
- Jake J. Hecla
- & Areg Danagoulian
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Article
| Open AccessSize-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles
Light-driven carbon dioxide conversion into fuels provides a nature-inspired strategy to combat climate change, but how materials do so remains a challenge. Here, the authors prepare metal–semiconductor composites and find platinum-nanoparticle size controls fuel selectivity and activity.
- Chunyang Dong
- , Cheng Lian
- & Jinlong Zhang
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Article
| Open AccessSingle rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions
Catalytic transformation of CH4 under mild conditions has implications to shale gas utilization. Here, the authors report the transformation of CH4 to acetic acid through coupling of CH4, CO and O2 on single-site Rh1O5 anchored in microporous aluminosilicates in liquid phase.
- Yu Tang
- , Yuting Li
- & Franklin (Feng) Tao
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Article
| Open AccessAdsorption-based atmospheric water harvesting device for arid climates
Harvesting water from the atmosphere is an important solution to water scarcity, but doing so in arid climates is highly challenging. Here, the authors develop a metal-organic framework-based water harvesting device that can deliver over 0.25 L of water per kg of adsorbent over a single cycle at relative humidities of 10–40% and at subzero dew points.
- Hyunho Kim
- , Sameer R. Rao
- & Evelyn N. Wang
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Article
| Open AccessCopper-surface-mediated synthesis of acetylenic carbon-rich nanofibers for active metal-free photocathodes
While photoelectrochemical devices combine light-absorption with fuel and electricity generation, their implementation is hampered by high costs and low output. Here, the authors synthesized acetylene-rich carbon fibers by copper-mediated polymerization for high-activity, metal-free photocathodes.
- Tao Zhang
- , Yang Hou
- & Xinliang Feng
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| Open AccessSurface passivation engineering strategy to fully-inorganic cubic CsPbI3 perovskites for high-performance solar cells
Inorganic cesium lead iodide perovskite is inherently more stable than the hybrid perovskites but it undergoes phase transition that degrades the solar cell performance. Here Li et al. stabilize it with poly-vinylpyrrolidone and obtain high efficiency of 10.74% with excellent thermal and moisture stability.
- Bo Li
- , Yanan Zhang
- & Longwei Yin
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Article
| Open AccessNanoscale kinetics of asymmetrical corrosion in core-shell nanoparticles
Understanding how catalysts corrode during use is crucial in developing new, durable devices. Here, the authors studied the real-time corrosion of core-shell palladium-platinum nanocubes by electron microscopy and found two competitive etching mechanisms to dominate catalyst degradation behavior.
- Hao Shan
- , Wenpei Gao
- & Jianbo Wu
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Article
| Open AccessUltra-thin enzymatic liquid membrane for CO2 separation and capture
Porous membranes show great promise for CO2 separation and capture, but are currently limited by a trade-off between permeance and selectivity. Here, the authors fabricate a bio-inspired, ultra-thin enzymatic liquid membrane that displays exceptional CO2 permeability and selectivity under ambient conditions.
- Yaqin Fu
- , Ying-Bing Jiang
- & C. Jeffrey Brinker
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Article
| Open AccessElucidating anionic oxygen activity in lithium-rich layered oxides
A reversible oxygen redox process contributes extra capacity and understanding this behavior is of high importance. Here, aided by resonant inelastic X-ray scattering, the authors reveal the distinctive anionic oxygen activity of battery electrodes with different transition metals.
- Jing Xu
- , Meiling Sun
- & Wei Tong
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Article
| Open AccessAtomic visualization of a non-equilibrium sodiation pathway in copper sulfide
Copper sulfide allows for high-performance sodium ion storage, yet its sodiation mechanism is poorly understood. Here, the authors examine the atomic structures of sodiated phases via in situ transmission electron microscopy, showing a non-equilibrium reaction pathway.
- Jae Yeol Park
- , Sung Joo Kim
- & Jong Min Yuk
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| Open AccessFormation of size-dependent and conductive phase on lithium iron phosphate during carbon coating
Coating the active materials of interest with carbon is a widely employed way to boost the performance of lithium ion batteries. Here the authors show the formation of a conductive phase on LiFePO4 during carbon coating, which is size, annealing temperature and reduction atmosphere dependent.
- Yulong Liu
- , Jian Liu
- & Xueliang Sun
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| Open AccessMonovalent manganese based anodes and co-solvent electrolyte for stable low-cost high-rate sodium-ion batteries
Sodium ion batteries offer more cost-effective storage than lithium and could be used for grid-scale energy storage. Here, the authors demonstrate a full cell based on a MnHCMn anode and an organic-aqueous cosolvent electrolyte. X-ray spectroscopy evidence further suggests the presence of Mn(I).
- Ali Firouzi
- , Ruimin Qiao
- & Colin D. Wessells
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Article
| Open AccessSodium enhances indium-gallium interdiffusion in copper indium gallium diselenide photovoltaic absorbers
Sodium doping is necessary to achieve high performance in polycrystalline chalcopyrite solar cells, but retards gallium interdiffusion, and thus efficiency optimisation. Here, Colombara et al. show that in contrast to the polycrystalline case, sodium accelerates atomic interdiffusion in monocrystalline samples.
- Diego Colombara
- , Florian Werner
- & Susanne Siebentritt
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Article
| Open AccessBioinspired leaves-on-branchlet hybrid carbon nanostructure for supercapacitors
One way to improve the performance of supercapacitors is to use hybrid carbon nanomaterials. Here the authors show a bioinspired electrode design with graphene petals and carbon nanotube arrays serving as leaves and branchlets, respectively. The structure affords excellent electrochemical characteristics.
- Guoping Xiong
- , Pingge He
- & Timothy S. Fisher
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Article
| Open AccessKinetics of lithium peroxide oxidation by redox mediators and consequences for the lithium–oxygen cell
The kinetics of Li2O2 oxidation is of high importance to the operation of Li–O2 batteries. Here the authors work on different types of mediators revealing the dependence of the kinetics on the nature of the redox active site and its steric hindrance.
- Yuhui Chen
- , Xiangwen Gao
- & Peter G. Bruce
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Article
| Open AccessOxidation-stable amine-containing adsorbents for carbon dioxide capture
Amine-containing solids are promising adsorbents for CO2 capture, but their low oxidative stability has hindered their application. Here, Choi and colleagues develop a strategy to poison the metal impurities present in poly(ethyleneimine)/silica adsorbents, significantly improving their stability towards oxidation.
- Kyungmin Min
- , Woosung Choi
- & Minkee Choi
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Article
| Open AccessChemisorption of polysulfides through redox reactions with organic molecules for lithium–sulfur batteries
Novel cathode design holds the key to enabling high performance lithium-sulfur batteries. Here the authors utilize anthraquinone to chemically stabilize polysulfides, revealing that the keto groups of anthraquinone play a critical role in forming strong Lewis acid-based chemical bonding.
- Ge Li
- , Xiaolei Wang
- & Zhongwei Chen
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Article
| Open AccessInference of field reversed configuration topology and dynamics during Alfvenic transients
It is important to understand the fast plasma dynamics in the operation of fusion plasma devices. Here the authors demonstrate the inference on the internal field reversed configuration magnetic topology and their occurrence during fast Alfvenic transient phenomena in C-2U device.
- J. A. Romero
- , S. A. Dettrick
- & Y. Mok
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Article
| Open AccessBiomimetic light-harvesting funnels for re-directioning of diffuse light
Sunlight harvesting and redirection is a promising concept for sustainable energy conversion, however losses have hindered progress. Here the authors construct a simple biomimetic device which minimises losses by using reservoirs of randomly-oriented dyes to funnel energy onto individual emitting parallel acceptors.
- Alexander Pieper
- , Manuel Hohgardt
- & Peter Jomo Walla
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Article
| Open AccessUltra-high thermal effusivity materials for resonant ambient thermal energy harvesting
Ambient environmental thermal fluctuations offer an abundant yet difficult to harvest renewable energy source, when compared to static thermal gradients. Here, by tuning the thermal effusivity of composite phase change materials, the authors are able to harvest energy from diurnal ambient temperature changes.
- Anton L. Cottrill
- , Albert Tianxiang Liu
- & Michael S. Strano
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| Open AccessProbing electrochemical reactions in organic cathode materials via in operando infrared spectroscopy
Metal-organic batteries are gaining traction as versatile, low-cost, and sustainable devices, although there are still few ways to probe internal behavior during use. Here, the authors explore organic-molecule structural changes within several battery systems by in operando infrared spectroscopy.
- Alen Vizintin
- , Jan Bitenc
- & Robert Dominko
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Article
| Open AccessNanostructuring one-dimensional and amorphous lithium peroxide for high round-trip efficiency in lithium-oxygen batteries
While lithium-oxygen batteries offer a green method to power vehicles, the sluggish decomposition of lithium peroxide limits device performance. Here, the authors direct lithium peroxide formation into amorphous nanostructures to enable its facile decomposition and improve charging efficiency.
- Arghya Dutta
- , Raymond A. Wong
- & Hye Ryung Byon
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| Open AccessEnergy use and life cycle greenhouse gas emissions of drones for commercial package delivery
The use of drones to deliver commercial packages is poised to become a new industry. Here the authors show that replacing truck delivery by drones can reduce greenhouse gas emissions and energy use when the drone size and additional warehousing requirements are limited.
- Joshuah K. Stolaroff
- , Constantine Samaras
- & Daniel Ceperley