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Direct imaging of Joule heating dynamics and temperature profiling inside a carbon nanotube interconnect
The use of carbon nanotubes in nanoelectronics requires an understanding of their resistive, or Joule, heating at interconnects. Here, Joule heating dynamics are imaged in real time by following the evolution of resistive hot spots with a transmission electron microscope.
- Pedro M.F.J. Costa
- , Ujjal K. Gautam
- & Dmitri Golberg
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| Open AccessAdvantageous grain boundaries in iron pnictide superconductors
High critical temperature superconductors could be used to produce ideal electric power lines, but the misalignment of crystalline grain boundaries reduces current density. Here, pnictide superconductors are found to be more tolerant to misaligned grain boundaries than cuprates.
- Takayoshi Katase
- , Yoshihiro Ishimaru
- & Hideo Hosono
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Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
Replacing platinum in polymer-electrolyte-membrane fuel cells with iron-based catalysts could provide low-cost power generators, but often leads to low power densities. Here, a new iron-based cathode catalyst is developed with enhanced power density, volumetric activity and mass-transport properties.
- Eric Proietti
- , Frédéric Jaouen
- & Jean-Pol Dodelet
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Encapsulation of single-molecule magnets in carbon nanotubes
Single-molecule magnets could be useful for the development of spintronic devices. Here single-molecule magnets are encapsulated in carbon nanotubes without affecting the properties of the guest molecules, which may be useful in the development of spintronic or high-density magnetic storage devices.
- Maria del Carmen Giménez-López
- , Fabrizio Moro
- & Andrei N. Khlobystov
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Porous covalent electron-rich organonitridic frameworks as highly selective sorbents for methane and carbon dioxide
Materials that can separate and capture carbon dioxide from power plant flue gases could help to stabilize atmospheric levels of the gas. Mohantyet al. develop inexpensive porous organonitridic frameworks with high selectivity and sorption capacities for carbon dioxide and methane.
- Paritosh Mohanty
- , Lilian D. Kull
- & Kai Landskron
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| Open AccessProximity of iron pnictide superconductors to a quantum tricritical point
In some iron-based materials, unconventional superconductivity can emerge near a quantum phase transition where long-range magnetic order vanishes. Giovannettiet al.show that the magnetic quantum phase transition in an iron pnictide superconductor is very close to the quantum tricritical point.
- Gianluca Giovannetti
- , Carmine Ortix
- & José Lorenzana
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Confined propagation of covalent chemical reactions on single-walled carbon nanotubes
Covalent reactions on carbon nanotube surfaces typically occur at random positions on the hexagonal lattice. Denget al. show that Billups–Birch reductive alkylation takes place at, and propagates from, sp3defect sites, leading to confinement of the reaction fronts in the tubular direction.
- Shunliu Deng
- , Yin Zhang
- & YuHuang Wang
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| Open AccessMediatorless high-power glucose biofuel cells based on compressed carbon nanotube-enzyme electrodes
Glucose biofuel cells can be used to produce clean energy from renewable sources, but their use is limited by poor stability and low power output. In this study, bioelectrodes are fabricated using carbon nanotubes and the resulting biofuel cells have improved stability and power.
- Abdelkader Zebda
- , Chantal Gondran
- & Serge Cosnier
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Collective fluorescence enhancement in nanoparticle clusters
Single nanoparticles are known to emit light intermittently, or 'blink', but the mechanisms describing this phenomenon are not fully understood. This study demonstrates that, for small clusters of blinking nanoparticles, the number of particles within a cluster dramatically influences blinking time.
- Siying Wang
- , Claudia Querner
- & Marija Drndic
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| Open AccessPromotion of water-mediated carbon removal by nanostructured barium oxide/nickel interfaces in solid oxide fuel cells
Anodes composed of nickel/yttria-stabilized zirconia in solid oxide fuel cells are known to suffer from coking, which reduces their performance. Here, Yang and colleagues report a new barium oxide/nickel anode, which efficiently oxidizes fuel with minimum carbon buildup.
- Lei Yang
- , YongMan Choi
- & Meilin Liu
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Burning vegetation produces cyanohydrins that liberate cyanide and stimulate seed germination
Cyanide, a known plant defence compound, can also stimulate seed germination. Flemattiet al. show that glyceronitrile is produced in wildfire smoke, which can release cyanide and stimulate seed germination of fire-responsive plant species, thus serving as an ecological store of cyanide.
- Gavin R. Flematti
- , David J. Merritt
- & Emilio L. Ghisalberti
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| Open AccessColossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer
Negative thermal expansion—contraction upon heating—is an unusual process that may be exploited to produce materials with zero or other controlled thermal expansion values. Azumaet al. observe negative thermal expansion in BiNiO3which is a result of Bi/Ni charge-transfer transitions.
- Masaki Azuma
- , Wei-tin Chen
- & J. Paul Attfield
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Atomistic mechanism for the activation and desensitization of an AMPA-subtype glutamate receptor
Upon agonist binding, ionotropic glutamate receptors are activated and then become desensitized, but the detailed molecular events of this process are unclear. Here, molecular dynamics simulations are used to probe how conformational changes of the ligand-binding domain are transmitted to the transmembrane domain.
- Hao Dong
- & Huan-Xiang Zhou
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| Open AccessDetermination of nanoparticle size distribution together with density or molecular weight by 2D analytical ultracentrifugation
Nanoparticles continue to find research and industrial applications, but no single technique exists to characterise their physical properties. Now, an analytical ultracentrifugation method is described which allows the simulataneous determination of nanoparticle size, density and molecular weight distribution.
- Randy P. Carney
- , Jin Young Kim
- & Osman M. Bakr
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Stabilizing lithium–sulphur cathodes using polysulphide reservoirs
Lithium–sulphur batteries may achieve higher energy densities than conventional lithium-ion cells, but the dissolution of sulphur intermediates is a continuing challenge. Here this problem is overcome using a cathode with a mesoporous structure that is able to accommodate intermediate polysulphide anions.
- Xiulei Ji
- , Scott Evers
- & Linda F. Nazar
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| Open AccessRevealing the molecular structure of single-molecule junctions in different conductance states by fishing-mode tip-enhanced Raman spectroscopy
The conductance of single-molecule junctions is affected by the structure of the molecule and how it is bound to the electrodes, which may be examined using Raman spectroscopy. Liuet al. have developed 'fishing-mode' tip-enhanced Raman spectroscopy, which allows the simultaneous determination of conductance and Raman spectra.
- Zheng Liu
- , Song-Yuan Ding
- & Zhong-Qun Tian
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Mutual adaptation of a membrane protein and its lipid bilayer during conformational changes
The detailed interactions of membrane proteins with their lipid environment are poorly understood. Sonntaget al. use low-resolution X-ray crystallographic data and molecular dynamics simulations to study the manner in which the sarcoendoplasmic reticulum Ca2+–ATPase adapts to different membrane environments.
- Yonathan Sonntag
- , Maria Musgaard
- & Lea Thøgersen
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| Open AccessLarge-scale single-chirality separation of single-wall carbon nanotubes by simple gel chromatography
Large-scale separation of single-wall carbon nanotubes into populations of single chirality is a significant challenge in the practical application of nanotubes. Now, using multicolumn gel chromatography, the large-scale separation of 13 different carbon nanotube species is achieved.
- Huaping Liu
- , Daisuke Nishide
- & Hiromichi Kataura
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Two-dimensional enzyme diffusion in laterally confined DNA monolayers
Little is known about the effects of molecular crowding and confinement on biomolecule function. Castronovoet al. investigate the reactions of restriction enzymes with DNA confined in bushy matrices and find that the enzymes enter at the side of the matrix before diffusing two-dimensionally.
- Matteo Castronovo
- , Agnese Lucesoli
- & Giacinto Scoles
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Synthesis of hexagonal close-packed gold nanostructures
Solid gold is most stable as a face-centred cubic structure, and stable colloidal gold with hexagonal close packing has not been produced. Huanget al.prepare square gold sheets with hexagonal close packing that are stable under ambient conditions.
- Xiao Huang
- , Shaozhou Li
- & Hua Zhang
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Size and mechanics effects in surface-induced melting of nanoparticles
Melting-related phenomena are of fundamental and applied interest, but the melting theory is poorly understood. Levitas and Samani develop an advanced phase-field theory of melting coupled to mechanics that resolves existing contradictions and reveals the features of melting phenomena.
- Valery I Levitas
- & Kamran Samani
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| Open AccessReversible temperature regulation of electrical and thermal conductivity using liquid–solid phase transitions
Temperature-controlled regulation of thermal conductivity is difficult to achieve because thermal properties do not change significantly through solid-state phase transitions. Here temperature control of thermal conductivities is demonstrated using liquid–solid phase transitions in a nanoparticle suspension.
- Ruiting Zheng
- , Jinwei Gao
- & Gang Chen
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| Open AccessNano-engineered electron–hole exchange interaction controls exciton dynamics in core–shell semiconductor nanocrystals
Electron–hole exchange interaction is an intrinsic property of semiconductors, which affects their fine structure. Brovelliet al. demonstrate a nanoengineering-based approach that provides control over the exchange interaction energy at nearly constant emission energy, which cannot be carried out using core-only nanocrystals.
- S. Brovelli
- , R.D. Schaller
- & V.I. Klimov
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Molecular dynamics of single-particle impacts predicts phase diagrams for large scale pattern formation
Energetic particle irradiation can lead to surface smoothing, pattern formation or degradation of the structural integrity of nuclear reactor components. Here, molecular dynamics simulations are used to study the mechanisms that determine the transitions between these disparate processes.
- Scott A. Norris
- , Juha Samela
- & Michael J. Aziz
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| Open AccessGapless spin liquid of an organic triangular compound evidenced by thermodynamic measurements
Frustrated magnetic systems can form an exotic quantum spin-liquid ground state, in which strongly correlated spins fluctuate in the spin lattices. Here, the low-temperature electronic state of a charge-transfer compound is found to form a gapless spin liquid.
- Satoshi Yamashita
- , Takashi Yamamoto
- & Reizo Kato
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LTD is a protein required for sorting light-harvesting chlorophyll-binding proteins to the chloroplast SRP pathway
Chloroplast proteins are synthesized in the cytosol and imported into the chloroplast before being delivered to the thylakoids. The authors report that an ankyrin-repeat protein, LTD, is essential for the routing of chlorophyll-binding proteins to the signal recognition particle pathway.
- Min Ouyang
- , Xiaoyi Li
- & Lixin Zhang
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| Open AccessThe Meissner effect in a strongly underdoped cuprate above its critical temperature
In the pseudogap state of cuprates, although diamagnetic signals have been detected, a Meissner effect has never been observed. Morenzoni and colleagues probe the local diamagnetic response in the normal state of an underdoped layer showing that a 'barrier' layer exhibits a Meissner effect.
- Elvezio Morenzoni
- , Bastian M. Wojek
- & Ivan Božović
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A flow-microreactor approach to protecting-group-free synthesis using organolithium compounds
Protecting-group-free synthesis has received significant attention, but organolithium species react rapidly with ketones necessitating protection of the ketone carbonyl. Here, a flow-microreactor approach is described that allows protecting-group-free organolithium reactions in the presence of ketones.
- Heejin Kim
- , Aiichiro Nagaki
- & Jun-ichi Yoshida
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| Open AccessQuantum interference of large organic molecules
Observing superposition states of mesoscopic quantum systems is an ongoing challenge. Gerlichet al. report quantum interference of large tailor-made organic compounds, demonstrating delocalization and the quantum wave nature of entire molecules composed of up to 430 atoms.
- Stefan Gerlich
- , Sandra Eibenberger
- & Markus Arndt
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Adhesive water networks facilitate binding of protein interfaces
The formation of hydrophilic protein–protein interactions cannot be explained by charge–charge interactions. Here, molecular simulations reveal that water forms an adhesive hydrogen-bonded network between proteins, stabilizing intermediate states before the bound complex forms.
- Mazen Ahmad
- , Wei Gu
- & Volkhard Helms
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The lifetime of the deviations from bulk behaviour in polymers confined at the nanoscale
Monitoring the impact of annealing on nanometre-thick polymer layers provides new insight into the changes in the performance of macromolecular materials. Here, the authors present results showing a correlation between the deviations from bulk behaviour and the growth of an irreversibly adsorbed layer.
- Simone Napolitano
- & Michael Wübbenhorst
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| Open AccessA new method to position and functionalize metal-organic framework crystals
Metal-organic frameworks (MOFs) have potential catalysis, filtration and sensing applications, but device fabrication will require controlled MOF growth. Here, α-hopeite microparticles are used to achieve spatial control of MOF nucleation, and accelerate MOF growth.
- Paolo Falcaro
- , Anita J. Hill
- & Dario Buso
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Organocatalytic enantioselective β-functionalization of aldehydes by oxidation of enamines and their application in cascade reactions
The transformation of iminium ions to enamines has been used extensively in organocatalysis, but conversion of enamines to iminium species has not been exploited. In this study, oxidative enamine catalysis allows the conversion of enamines to iminium ions and the direct asymmetric β-functionalization of simple aldehydes.
- Shi-Lei Zhang
- , He-Xin Xie
- & Wei Wang
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Imaging oxygen defects and their motion at a manganite surface
Oxygen diffusion processes are critical for the catalytic action of manganites but a full understanding of these processes is elusive. The authors perform atomic resolution scanning tunnelling microscopy imaging of layered manganites and show oxygen and defect dynamics on these surfaces.
- B. Bryant
- , Ch. Renner
- & G. Aeppli
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Metallosupramolecular self-assembly of a universal 3-ravel
There has been recent progress in the synthesis of complex intertwined supramolecular topologies. In this study, Liet al.report the self-assembly of an intertwined structure based on a universal 3-ravel.
- Feng Li
- , Jack K. Clegg
- & George V. Meehan
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Porous organic molecular solids by dynamic covalent scrambling
The construction of porous solids from discrete organic molecules usually involves the formation of regular porous crystals. In this study, a covalent scrambling reaction gives molecules with a range of shapes that do not pack effectively — manipulation of the reagent ratio allows fine control of porosity.
- Shan Jiang
- , James T. A. Jones
- & Andrew I. Cooper
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Chemical processes in the deep interior of Uranus
The unusual magnetic fields of Uranus and Neptune are important considerations when developing hydrodynamic models of the planetary interiors. In this study, molecular dynamics simulations are used to study how chemical processes could create the interior structures predicted from the planets' magnetic fields.
- Ricky Chau
- , Sebastien Hamel
- & William J. Nellis
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Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene
Separation of acetylene and ethylene is an important industrial challenge, which may be aided by selectively adsorbant materials. In this study, a metal-organic framework material is reported, which allows highly selective separation of acetylene and ethylene.
- Sheng-Chang Xiang
- , Zhangjing Zhang
- & Banglin Chen
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Ionic polypeptides with unusual helical stability
Water-soluble peptides with stable α-helical conformations are desirable for a range of applications, but incorporating charged residues to improve solubility usually leads to reduced helical stability. Here, polypeptides produced from amino acids with elongated charged side chains are found to be water soluble and exhibit very high helical stability.
- Hua Lu
- , Jing Wang
- & Jianjun Cheng
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Vibrational dynamics and surface structure of amorphous selenium
Defining the structure of amorphous solids is a challenge because of their lack of structural order. In this study, the authors combine experiment and theory to analyse the surface of amorphous selenium, and show that the differences between surface and bulk are attributable to a particular type of coordination defect.
- T. Scopigno
- , W. Steurer
- & T. Wagner
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Mixtures of planetary ices at extreme conditions
The interiors of outer solar planets are believed to contain water–methane mixtures that are subject to extreme pressures. Lee and Scandolo use molecular dynamics simulations to show that at high pressures there can be enhanced mixing and ionization, with consequences for the origin of the planetary magnetic field.
- Mal-Soon Lee
- & Sandro Scandolo
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A bacterial proteorhodopsin proton pump in marine eukaryotes
Proteorhodopsin is used by prokaryotes to generate energy from light. In this study, the authors describe a prokaryote-to-eukaryote horizontal gene transfer of a bacterial proteorhodopsin gene to dinoflagellates, suggesting that these eukaryotes can also use proteorhodopsin to obtain light and produce energy.
- Claudio H. Slamovits
- , Noriko Okamoto
- & Patrick J. Keeling
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| Open AccessMolecular decoding using luminescence from an entangled porous framework
Distinguishing closely related molecules using chemosensor materials is a continuing challenge. Here, an entangled porous coordination polymer is developed, which confines volatile organic compounds, and allows photoluminescence-based distinction of structurally similar aromatic molecules.
- Yohei Takashima
- , Virginia Martínez Martínez
- & Susumu Kitagawa
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| Open AccessCrystallographic observation of 'induced fit' in a cryptophane host–guest model system
Cryptophane-A is a prototypical organic host molecule that binds reversibly to neutral guest molecules. Taratulaet al.report X-ray structures of cryptophane-A complexed with a range of host molecules to show that the cryptophane host–guest system exhibits ‘induced fit’.
- Olena Taratula
- , P. Aru Hill
- & Ivan J. Dmochowski
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Spherical hyperlens for two-dimensional sub-diffractional imaging at visible frequencies
Although hyperlenses made of metamaterials can image sub-diffraction-limited objects, they are limited to one-dimensional magnification and ultraviolet frequencies. Here, the authors demonstrate a spherical hyperlens for visible light far-field imaging, with a resolution of 160 nm in both lateral dimensions.
- Junsuk Rho
- , Ziliang Ye
- & Xiang Zhang
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Article
| Open AccessSingle-molecule identification via electric current noise
Molecular fluctuations are a source of noise that can impede single-molecule identification. Here, quantum-fluctuation-induced inelastic noise is observed as current fluctuations in individual molecules, suggesting that inelastic noise could be used as a molecular signature.
- Makusu Tsutsui
- , Masateru Taniguchi
- & Tomoji Kawai
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Pseudogap in a thin film of a conventional superconductor
In high-temperature superconductors, a very low density of states, the pseudogap, exists even above the critical temperature. Here, the authors show that this is also the case for a conventional superconductor, titanium nitride thin films, and that this pseudogap is induced by superconducting fluctuations.
- Benjamin Sacépé
- , Claude Chapelier
- & Marc Sanquer
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| Open AccessAll-linear time reversal by a dynamic artificial crystal
Signal processing by time reversal has thus far only been realized through nonlinear mechanisms. The authors describe an all-linear, and thus low-power, time-reversal process based on frequency inversion in a dynamically controlled artificial periodic structure, a dynamic magnonic crystal.
- Andrii V. Chumak
- , Vasil S. Tiberkevich
- & Burkard Hillebrands
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| Open AccessStretching fibronectin fibres disrupts binding of bacterial adhesins by physically destroying an epitope
Bacteria express adhesive proteins on their surface that recognize fibronectin. Using a mechanical stretch assay and steered molecular dynamics, Chabriaet al. demonstrate that the binding of a bacterial adhesin to fibronectin is mechanoregulated, suggesting that bacteria can sense tissue fibre stretching.
- Mamta Chabria
- , Samuel Hertig
- & Viola Vogel
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